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Dinitrosylbis[tris(4-methylphenyl)phosphane]iron
The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2) L (2)],...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052133/ https://www.ncbi.nlm.nih.gov/pubmed/21522262 http://dx.doi.org/10.1107/S160053681100465X |
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| author | Jones, Myron W. Powell, Douglas R. Richter-Addo, George B. |
| author_facet | Jones, Myron W. Powell, Douglas R. Richter-Addo, George B. |
| author_sort | Jones, Myron W. |
| collection | PubMed |
| description | The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2) L (2)], with L = P(C(6)H(4)-p-CH(3))(3). There are two crystallographically independent but chemically equal molecules per asymmetric unit. The iron atom in each molecule is tetrahedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16)°. |
| format | Text |
| id | pubmed-3052133 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30521332011-04-26 Dinitrosylbis[tris(4-methylphenyl)phosphane]iron Jones, Myron W. Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2) L (2)], with L = P(C(6)H(4)-p-CH(3))(3). There are two crystallographically independent but chemically equal molecules per asymmetric unit. The iron atom in each molecule is tetrahedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16)°. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052133/ /pubmed/21522262 http://dx.doi.org/10.1107/S160053681100465X Text en © Jones et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jones, Myron W. Powell, Douglas R. Richter-Addo, George B. Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title | Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title_full | Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title_fullStr | Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title_full_unstemmed | Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title_short | Dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| title_sort | dinitrosylbis[tris(4-methylphenyl)phosphane]iron |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052133/ https://www.ncbi.nlm.nih.gov/pubmed/21522262 http://dx.doi.org/10.1107/S160053681100465X |
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