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Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium

The complete mol­ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa­hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithio­carbamate anions and two pyridin...

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Detalles Bibliográficos
Autores principales: Broker, Grant A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052135/
https://www.ncbi.nlm.nih.gov/pubmed/21522253
http://dx.doi.org/10.1107/S1600536811004508
Descripción
Sumario:The complete mol­ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa­hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithio­carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine­aldazine (or 4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene}meth­yl]pyridine) mol­ecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In the crystal, mol­ecules are connected into a supra­molecular chain via O—H⋯N hydrogen bonds involving the 4-pyridine­aldazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing.