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Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2) S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN (1))cadmium
The complete molecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octahedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithiocarbamate anions and two pyridin...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052135/ https://www.ncbi.nlm.nih.gov/pubmed/21522253 http://dx.doi.org/10.1107/S1600536811004508 |
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author | Broker, Grant A. Tiekink, Edward R. T. |
author_facet | Broker, Grant A. Tiekink, Edward R. T. |
author_sort | Broker, Grant A. |
collection | PubMed |
description | The complete molecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octahedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithiocarbamate anions and two pyridine N atoms derived from two monodentate 4-pyridinealdazine (or 4-{[(pyridin-4-ylmethylidene)hydrazinylidene}methyl]pyridine) molecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In the crystal, molecules are connected into a supramolecular chain via O—H⋯N hydrogen bonds involving the 4-pyridinealdazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing. |
format | Text |
id | pubmed-3052135 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30521352011-04-26 Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2) S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN (1))cadmium Broker, Grant A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octahedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithiocarbamate anions and two pyridine N atoms derived from two monodentate 4-pyridinealdazine (or 4-{[(pyridin-4-ylmethylidene)hydrazinylidene}methyl]pyridine) molecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In the crystal, molecules are connected into a supramolecular chain via O—H⋯N hydrogen bonds involving the 4-pyridinealdazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052135/ /pubmed/21522253 http://dx.doi.org/10.1107/S1600536811004508 Text en © Broker and Tiekink 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Broker, Grant A. Tiekink, Edward R. T. Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2) S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN (1))cadmium |
title | Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2)
S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN
(1))cadmium |
title_full | Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2)
S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN
(1))cadmium |
title_fullStr | Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2)
S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN
(1))cadmium |
title_full_unstemmed | Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2)
S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN
(1))cadmium |
title_short | Bis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ(2)
S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN
(1))cadmium |
title_sort | bis[n-(2-hydroxyethyl)-n-propyldithiocarbamato-κ(2)
s,s′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κn
(1))cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052135/ https://www.ncbi.nlm.nih.gov/pubmed/21522253 http://dx.doi.org/10.1107/S1600536811004508 |
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