Cargando…

Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium

The complete mol­ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa­hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithio­carbamate anions and two pyridin...

Descripción completa

Detalles Bibliográficos
Autores principales: Broker, Grant A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052135/
https://www.ncbi.nlm.nih.gov/pubmed/21522253
http://dx.doi.org/10.1107/S1600536811004508
_version_ 1782199635788431360
author Broker, Grant A.
Tiekink, Edward R. T.
author_facet Broker, Grant A.
Tiekink, Edward R. T.
author_sort Broker, Grant A.
collection PubMed
description The complete mol­ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa­hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithio­carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine­aldazine (or 4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene}meth­yl]pyridine) mol­ecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In the crystal, mol­ecules are connected into a supra­molecular chain via O—H⋯N hydrogen bonds involving the 4-pyridine­aldazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing.
format Text
id pubmed-3052135
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30521352011-04-26 Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium Broker, Grant A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa­hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S′-chelating dithio­carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine­aldazine (or 4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene}meth­yl]pyridine) mol­ecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In the crystal, mol­ecules are connected into a supra­molecular chain via O—H⋯N hydrogen bonds involving the 4-pyridine­aldazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052135/ /pubmed/21522253 http://dx.doi.org/10.1107/S1600536811004508 Text en © Broker and Tiekink 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Broker, Grant A.
Tiekink, Edward R. T.
Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title_full Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title_fullStr Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title_full_unstemmed Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title_short Bis[N-(2-hy­droxy­eth­yl)-N-propyl­dithio­carbamato-κ(2) S,S′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κN (1))cadmium
title_sort bis[n-(2-hy­droxy­eth­yl)-n-propyl­dithio­carbamato-κ(2) s,s′]bis­(4-{[(pyridin-4-yl­methyl­idene)hydrazinyl­idene]meth­yl}pyridine-κn (1))cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052135/
https://www.ncbi.nlm.nih.gov/pubmed/21522253
http://dx.doi.org/10.1107/S1600536811004508
work_keys_str_mv AT brokergranta bisn2hydroxyethylnpropyldithiocarbamatok2ssbis4pyridin4ylmethylidenehydrazinylidenemethylpyridinekn1cadmium
AT tiekinkedwardrt bisn2hydroxyethylnpropyldithiocarbamatok2ssbis4pyridin4ylmethylidenehydrazinylidenemethylpyridinekn1cadmium