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4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)

The asymmetric unit of the title salt adduct, C(6)H(13)N(2)O(+)·C(8)H(5)O(4) (−)·C(8)H(6)O(4), comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct mol­ecule. These form a two-dimensional hydrogen-bonded network through head-to-tail cation–anion–adduct mol­ecul...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052136/
https://www.ncbi.nlm.nih.gov/pubmed/21522329
http://dx.doi.org/10.1107/S1600536811003825
Descripción
Sumario:The asymmetric unit of the title salt adduct, C(6)H(13)N(2)O(+)·C(8)H(5)O(4) (−)·C(8)H(6)O(4), comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct mol­ecule. These form a two-dimensional hydrogen-bonded network through head-to-tail cation–anion–adduct mol­ecule inter­actions which include a cyclic heteromolecular amide–carboxyl­ate motif [graph set R (2) (2)(8)], conjoint cyclic R (2) (2)(6) and R (3) (3)(10) piperidinium N—H⋯O(carbox­yl) associations, as well as strong carboxyl O—H⋯O(carbox­yl) hydrogen bonds.