4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)

The asymmetric unit of the title salt adduct, C(6)H(13)N(2)O(+)·C(8)H(5)O(4) (−)·C(8)H(6)O(4), comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct mol­ecule. These form a two-dimensional hydrogen-bonded network through head-to-tail cation–anion–adduct mol­ecul...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052136/
https://www.ncbi.nlm.nih.gov/pubmed/21522329
http://dx.doi.org/10.1107/S1600536811003825
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description The asymmetric unit of the title salt adduct, C(6)H(13)N(2)O(+)·C(8)H(5)O(4) (−)·C(8)H(6)O(4), comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct mol­ecule. These form a two-dimensional hydrogen-bonded network through head-to-tail cation–anion–adduct mol­ecule inter­actions which include a cyclic heteromolecular amide–carboxyl­ate motif [graph set R (2) (2)(8)], conjoint cyclic R (2) (2)(6) and R (3) (3)(10) piperidinium N—H⋯O(carbox­yl) associations, as well as strong carboxyl O—H⋯O(carbox­yl) hydrogen bonds.
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spelling pubmed-30521362011-04-26 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1) Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt adduct, C(6)H(13)N(2)O(+)·C(8)H(5)O(4) (−)·C(8)H(6)O(4), comprises one isonipecotamide cation, a hydrogen phthalate anion and a phthalic acid adduct mol­ecule. These form a two-dimensional hydrogen-bonded network through head-to-tail cation–anion–adduct mol­ecule inter­actions which include a cyclic heteromolecular amide–carboxyl­ate motif [graph set R (2) (2)(8)], conjoint cyclic R (2) (2)(6) and R (3) (3)(10) piperidinium N—H⋯O(carbox­yl) associations, as well as strong carboxyl O—H⋯O(carbox­yl) hydrogen bonds. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3052136/ /pubmed/21522329 http://dx.doi.org/10.1107/S1600536811003825 Text en © Smith and Wermuth 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title_full 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title_fullStr 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title_full_unstemmed 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title_short 4-Carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
title_sort 4-carbamoylpiperidinium 2-carb­oxy­benzoate–benzene-1,2-dicarb­oxy­lic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052136/
https://www.ncbi.nlm.nih.gov/pubmed/21522329
http://dx.doi.org/10.1107/S1600536811003825
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