Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide

In the [Fe(4,4′-bit)(3)](2+) (4,4′-bit is 4,4′-bi-1,3-thia­zole) cation of the title compound, [Fe(C(6)H(4)N(2)S(2))(3)][FeBr(4)]Br, the Fe(II) atom (3 symmetry) is six-coordinated in a distorted octa­hedral geometry by six N atoms from three 4,4′-bit ligands. In the [FeBr(4)](−) anion, the Fe(III)...

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Detalles Bibliográficos
Autores principales: Abedi, Anita, Amani, Vahid, Safari, Nasser
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052137/
https://www.ncbi.nlm.nih.gov/pubmed/21522247
http://dx.doi.org/10.1107/S1600536811004181
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author Abedi, Anita
Amani, Vahid
Safari, Nasser
author_facet Abedi, Anita
Amani, Vahid
Safari, Nasser
author_sort Abedi, Anita
collection PubMed
description In the [Fe(4,4′-bit)(3)](2+) (4,4′-bit is 4,4′-bi-1,3-thia­zole) cation of the title compound, [Fe(C(6)H(4)N(2)S(2))(3)][FeBr(4)]Br, the Fe(II) atom (3 symmetry) is six-coordinated in a distorted octa­hedral geometry by six N atoms from three 4,4′-bit ligands. In the [FeBr(4)](−) anion, the Fe(III) atom (3 symmetry) is four-coordinated in a distorted tetra­hedral geometry. In the crystal, inter­molecular C—H⋯Br hydrogen bonds and Br⋯π inter­actions [Br⋯centroid distances = 3.562 (3) and 3.765 (2) Å] link the cations and anions, stabilizing the structure.
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spelling pubmed-30521372011-04-26 Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide Abedi, Anita Amani, Vahid Safari, Nasser Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the [Fe(4,4′-bit)(3)](2+) (4,4′-bit is 4,4′-bi-1,3-thia­zole) cation of the title compound, [Fe(C(6)H(4)N(2)S(2))(3)][FeBr(4)]Br, the Fe(II) atom (3 symmetry) is six-coordinated in a distorted octa­hedral geometry by six N atoms from three 4,4′-bit ligands. In the [FeBr(4)](−) anion, the Fe(III) atom (3 symmetry) is four-coordinated in a distorted tetra­hedral geometry. In the crystal, inter­molecular C—H⋯Br hydrogen bonds and Br⋯π inter­actions [Br⋯centroid distances = 3.562 (3) and 3.765 (2) Å] link the cations and anions, stabilizing the structure. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052137/ /pubmed/21522247 http://dx.doi.org/10.1107/S1600536811004181 Text en © Abedi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abedi, Anita
Amani, Vahid
Safari, Nasser
Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title_full Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title_fullStr Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title_full_unstemmed Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title_short Tris(4,4′-bi-1,3-thia­zole-κ(2) N,N′)iron(II) tetra­bromidoferrate(III) bromide
title_sort tris(4,4′-bi-1,3-thia­zole-κ(2) n,n′)iron(ii) tetra­bromidoferrate(iii) bromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052137/
https://www.ncbi.nlm.nih.gov/pubmed/21522247
http://dx.doi.org/10.1107/S1600536811004181
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AT amanivahid tris44bi13thiazolek2nnironiitetrabromidoferrateiiibromide
AT safarinasser tris44bi13thiazolek2nnironiitetrabromidoferrateiiibromide

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