Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc

In the title complex, [Zn(NCO)(2)(C(7)H(8)N(4))(2)], the Zn(II) ion exhibits a distorted tetra­hedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions...

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Detalles Bibliográficos
Autores principales: Caballero, Ana B., Quirós, Miguel, Rodríguez-Diéguez, Antonio, Salas, Juan M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052141/
https://www.ncbi.nlm.nih.gov/pubmed/21522274
http://dx.doi.org/10.1107/S1600536811005769
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author Caballero, Ana B.
Quirós, Miguel
Rodríguez-Diéguez, Antonio
Salas, Juan M.
author_facet Caballero, Ana B.
Quirós, Miguel
Rodríguez-Diéguez, Antonio
Salas, Juan M.
author_sort Caballero, Ana B.
collection PubMed
description In the title complex, [Zn(NCO)(2)(C(7)H(8)N(4))(2)], the Zn(II) ion exhibits a distorted tetra­hedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions inter­acting by their N atoms. Supra­molecular dimers are generated by stacking inter­actions between the pyrimidine rings of two ligands related by an inversion center [centroid–centroid distance = 3.5444 (18) Å].
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spelling pubmed-30521412011-04-26 Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc Caballero, Ana B. Quirós, Miguel Rodríguez-Diéguez, Antonio Salas, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(NCO)(2)(C(7)H(8)N(4))(2)], the Zn(II) ion exhibits a distorted tetra­hedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions inter­acting by their N atoms. Supra­molecular dimers are generated by stacking inter­actions between the pyrimidine rings of two ligands related by an inversion center [centroid–centroid distance = 3.5444 (18) Å]. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052141/ /pubmed/21522274 http://dx.doi.org/10.1107/S1600536811005769 Text en © Caballero et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Caballero, Ana B.
Quirós, Miguel
Rodríguez-Diéguez, Antonio
Salas, Juan M.
Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title_full Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title_fullStr Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title_full_unstemmed Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title_short Bis(cyanato-κN)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN (3))zinc
title_sort bis(cyanato-κn)bis­(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κn (3))zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052141/
https://www.ncbi.nlm.nih.gov/pubmed/21522274
http://dx.doi.org/10.1107/S1600536811005769
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