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Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]

In the title coordination polymer, {[Tb(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tb(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two adjacent monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TbNO(7) coordina...

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Detalles Bibliográficos
Autores principales: Lv, Dong-Yu, Gao, Zhu-Qing, Gu, Jin-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052142/
https://www.ncbi.nlm.nih.gov/pubmed/21522284
http://dx.doi.org/10.1107/S1600536811005447
Descripción
Sumario:In the title coordination polymer, {[Tb(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tb(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two adjacent monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TbNO(7) coordination environment. The anions bridge adjacent Tb(III) ions into double chains. Adjacent chains are further connected into sheets parallel to (10[Image: see text]). O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional network.