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Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]

In the title coordination polymer, {[Tb(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tb(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two adjacent monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TbNO(7) coordina...

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Detalles Bibliográficos
Autores principales: Lv, Dong-Yu, Gao, Zhu-Qing, Gu, Jin-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052142/
https://www.ncbi.nlm.nih.gov/pubmed/21522284
http://dx.doi.org/10.1107/S1600536811005447
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author Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
author_facet Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
author_sort Lv, Dong-Yu
collection PubMed
description In the title coordination polymer, {[Tb(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tb(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two adjacent monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TbNO(7) coordination environment. The anions bridge adjacent Tb(III) ions into double chains. Adjacent chains are further connected into sheets parallel to (10[Image: see text]). O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional network.
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spelling pubmed-30521422011-04-26 Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate] Lv, Dong-Yu Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Tb(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tb(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two adjacent monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TbNO(7) coordination environment. The anions bridge adjacent Tb(III) ions into double chains. Adjacent chains are further connected into sheets parallel to (10[Image: see text]). O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional network. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3052142/ /pubmed/21522284 http://dx.doi.org/10.1107/S1600536811005447 Text en © Lv et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lv, Dong-Yu
Gao, Zhu-Qing
Gu, Jin-Zhong
Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title_full Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title_fullStr Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title_full_unstemmed Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title_short Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(III)] monohydrate]
title_sort poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)terbium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052142/
https://www.ncbi.nlm.nih.gov/pubmed/21522284
http://dx.doi.org/10.1107/S1600536811005447
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