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(4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II)
The title Schiff base zinc(II) complex, [Zn(C(13)H(10)ClN(2)O)I(CH(3)OH)], was synthesized by the reaction of 5-chlorosalicylaldehyde, 2-aminomethylpyridine and zinc iodide in methanol. The Zn(II) atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff b...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052144/ https://www.ncbi.nlm.nih.gov/pubmed/21522248 http://dx.doi.org/10.1107/S160053681100417X |
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| author | Huang, Hong-Wei |
| author_facet | Huang, Hong-Wei |
| author_sort | Huang, Hong-Wei |
| collection | PubMed |
| description | The title Schiff base zinc(II) complex, [Zn(C(13)H(10)ClN(2)O)I(CH(3)OH)], was synthesized by the reaction of 5-chlorosalicylaldehyde, 2-aminomethylpyridine and zinc iodide in methanol. The Zn(II) atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff base ligand, one methanol O atom and one I atom, forming a distorted square-pyramidal geometry, with the I atom at the apical site. The dihedral angle between the benzene and pyridine rings is 22.9 (2)°. In the crystal, centrosymmetrically related molecules are linked through intermolecular O—H⋯O hydrogen bonds, forming dimers. |
| format | Text |
| id | pubmed-3052144 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30521442011-04-26 (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) Huang, Hong-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Schiff base zinc(II) complex, [Zn(C(13)H(10)ClN(2)O)I(CH(3)OH)], was synthesized by the reaction of 5-chlorosalicylaldehyde, 2-aminomethylpyridine and zinc iodide in methanol. The Zn(II) atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff base ligand, one methanol O atom and one I atom, forming a distorted square-pyramidal geometry, with the I atom at the apical site. The dihedral angle between the benzene and pyridine rings is 22.9 (2)°. In the crystal, centrosymmetrically related molecules are linked through intermolecular O—H⋯O hydrogen bonds, forming dimers. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052144/ /pubmed/21522248 http://dx.doi.org/10.1107/S160053681100417X Text en © Hong-Wei Huang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Huang, Hong-Wei (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title | (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title_full | (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title_fullStr | (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title_full_unstemmed | (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title_short | (4-Chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) |
| title_sort | (4-chloro-2-{[(pyridin-2-ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052144/ https://www.ncbi.nlm.nih.gov/pubmed/21522248 http://dx.doi.org/10.1107/S160053681100417X |
| work_keys_str_mv | AT huanghongwei 4chloro2pyridin2ylmethyliminomethylphenolatoiodidomethanolzincii |