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9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate
The title compound, C(36)H(31)N(2)O(3) (+),C(2)H(3)O(2) (−)·2C(2)H(5)OH, the product of a domino condensation of dibenzyl ketone with salicylic aldehyde and ammonium acetate, crystallized as the ethanol disolvate. The cation of the salt comprises a fused tricyclic system containing three six-membere...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052148/ https://www.ncbi.nlm.nih.gov/pubmed/21522325 http://dx.doi.org/10.1107/S160053681100376X |
| _version_ | 1782199638863904768 |
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| author | Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. |
| author_facet | Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. |
| author_sort | Anh, Le Tuan |
| collection | PubMed |
| description | The title compound, C(36)H(31)N(2)O(3) (+),C(2)H(3)O(2) (−)·2C(2)H(5)OH, the product of a domino condensation of dibenzyl ketone with salicylic aldehyde and ammonium acetate, crystallized as the ethanol disolvate. The cation of the salt comprises a fused tricyclic system containing three six-membered rings (piperidine, dihydro-2H-pyran and benzene). The piperidine ring has the usual chair conformation, while the dihydropyran ring adopts a slightly distorted sofa conformation. In the crystal, there are six (one intra- and five intermolecular) independent hydrogen-bonding interactions: the intermolecular hydrogen bonds link the cations and anions and ethanol solvent molecules into ribbons along [001]. The ribbons are stacked along the a axis. |
| format | Text |
| id | pubmed-3052148 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30521482011-04-26 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(31)N(2)O(3) (+),C(2)H(3)O(2) (−)·2C(2)H(5)OH, the product of a domino condensation of dibenzyl ketone with salicylic aldehyde and ammonium acetate, crystallized as the ethanol disolvate. The cation of the salt comprises a fused tricyclic system containing three six-membered rings (piperidine, dihydro-2H-pyran and benzene). The piperidine ring has the usual chair conformation, while the dihydropyran ring adopts a slightly distorted sofa conformation. In the crystal, there are six (one intra- and five intermolecular) independent hydrogen-bonding interactions: the intermolecular hydrogen bonds link the cations and anions and ethanol solvent molecules into ribbons along [001]. The ribbons are stacked along the a axis. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3052148/ /pubmed/21522325 http://dx.doi.org/10.1107/S160053681100376X Text en © Anh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Soldatova, Svetlana A. Khrustalev, Victor N. 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title | 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title_full | 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title_fullStr | 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title_full_unstemmed | 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title_short | 9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| title_sort | 9-[(2-hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10,13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.0(2,7)]trideca-2(7),3,5-triene acetate ethanol disolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052148/ https://www.ncbi.nlm.nih.gov/pubmed/21522325 http://dx.doi.org/10.1107/S160053681100376X |
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