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Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine

The title compound (systematic name: 2-{[2-(bis­{2-[({2-hy­droxy-5-[(4-meth­oxy­phen­yl)diazen­yl]phen­yl}methyl­idene)amino]­eth­yl}amino)­eth­yl]aza­niumylidenemeth­yl}-4-[(4-meth­oxy­phen­yl)diazen­yl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of th...

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Autores principales: Salehzadeh, Sadegh, Mahdavian, Mahsa, Khalaj, Mehdi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052149/
https://www.ncbi.nlm.nih.gov/pubmed/21522363
http://dx.doi.org/10.1107/S1600536811004405
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author Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
author_facet Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
author_sort Salehzadeh, Sadegh
collection PubMed
description The title compound (systematic name: 2-{[2-(bis­{2-[({2-hy­droxy-5-[(4-meth­oxy­phen­yl)diazen­yl]phen­yl}methyl­idene)amino]­eth­yl}amino)­eth­yl]aza­niumylidenemeth­yl}-4-[(4-meth­oxy­phen­yl)diazen­yl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of the tripodal mol­ecule are located close to each other and an intra­molecular hydrogen bond occurs in each arm (O—H⋯N in two arms and N—H⋯O in the zwitterionic arm). The dihedral angles between the aromatic rings in the three arms are 16.36 (14), 23.94 (14) and, for the zwitterionic arm, 37.14 (14)°. In the crystal, a weak inter­moleclar N—H⋯O hydrogen bond occurs.
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spelling pubmed-30521492011-04-26 Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound (systematic name: 2-{[2-(bis­{2-[({2-hy­droxy-5-[(4-meth­oxy­phen­yl)diazen­yl]phen­yl}methyl­idene)amino]­eth­yl}amino)­eth­yl]aza­niumylidenemeth­yl}-4-[(4-meth­oxy­phen­yl)diazen­yl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of the tripodal mol­ecule are located close to each other and an intra­molecular hydrogen bond occurs in each arm (O—H⋯N in two arms and N—H⋯O in the zwitterionic arm). The dihedral angles between the aromatic rings in the three arms are 16.36 (14), 23.94 (14) and, for the zwitterionic arm, 37.14 (14)°. In the crystal, a weak inter­moleclar N—H⋯O hydrogen bond occurs. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052149/ /pubmed/21522363 http://dx.doi.org/10.1107/S1600536811004405 Text en © Salehzadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title_full Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title_fullStr Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title_full_unstemmed Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title_short Zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
title_sort zwitterionic form of tris­({[5-(4-meth­oxy­phenyl­azo)salicyl­idene]amino}­eth­yl)amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052149/
https://www.ncbi.nlm.nih.gov/pubmed/21522363
http://dx.doi.org/10.1107/S1600536811004405
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AT khalajmehdi zwitterionicformoftris54methoxyphenylazosalicylideneaminoethylamine