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Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine
The title compound (systematic name: 2-{[2-(bis{2-[({2-hydroxy-5-[(4-methoxyphenyl)diazenyl]phenyl}methylidene)amino]ethyl}amino)ethyl]azaniumylidenemethyl}-4-[(4-methoxyphenyl)diazenyl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of th...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052149/ https://www.ncbi.nlm.nih.gov/pubmed/21522363 http://dx.doi.org/10.1107/S1600536811004405 |
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author | Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi |
author_facet | Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi |
author_sort | Salehzadeh, Sadegh |
collection | PubMed |
description | The title compound (systematic name: 2-{[2-(bis{2-[({2-hydroxy-5-[(4-methoxyphenyl)diazenyl]phenyl}methylidene)amino]ethyl}amino)ethyl]azaniumylidenemethyl}-4-[(4-methoxyphenyl)diazenyl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of the tripodal molecule are located close to each other and an intramolecular hydrogen bond occurs in each arm (O—H⋯N in two arms and N—H⋯O in the zwitterionic arm). The dihedral angles between the aromatic rings in the three arms are 16.36 (14), 23.94 (14) and, for the zwitterionic arm, 37.14 (14)°. In the crystal, a weak intermoleclar N—H⋯O hydrogen bond occurs. |
format | Text |
id | pubmed-3052149 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30521492011-04-26 Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound (systematic name: 2-{[2-(bis{2-[({2-hydroxy-5-[(4-methoxyphenyl)diazenyl]phenyl}methylidene)amino]ethyl}amino)ethyl]azaniumylidenemethyl}-4-[(4-methoxyphenyl)diazenyl]phenolate), C(48)H(48)N(10)O(6), exists as a zwitterion in the solid state. The three arms of the tripodal molecule are located close to each other and an intramolecular hydrogen bond occurs in each arm (O—H⋯N in two arms and N—H⋯O in the zwitterionic arm). The dihedral angles between the aromatic rings in the three arms are 16.36 (14), 23.94 (14) and, for the zwitterionic arm, 37.14 (14)°. In the crystal, a weak intermoleclar N—H⋯O hydrogen bond occurs. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052149/ /pubmed/21522363 http://dx.doi.org/10.1107/S1600536811004405 Text en © Salehzadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title | Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title_full | Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title_fullStr | Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title_full_unstemmed | Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title_short | Zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
title_sort | zwitterionic form of tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052149/ https://www.ncbi.nlm.nih.gov/pubmed/21522363 http://dx.doi.org/10.1107/S1600536811004405 |
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