Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)

In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl­pyridine ligand and one Cl atom, forming a distorted octa­hedral geometry. The Co(III) ion is displaced...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Qiong-Jie, Chen, Xiao-Hua, Jiang, Jiang, Cai, Bi-Qiong, Xie, Yong-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052150/
https://www.ncbi.nlm.nih.gov/pubmed/21522234
http://dx.doi.org/10.1107/S1600536811003321
Descripción
Sumario:In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl­pyridine ligand and one Cl atom, forming a distorted octa­hedral geometry. The Co(III) ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom.

Ejemplares similares