Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)

In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl­pyridine ligand and one Cl atom, forming a distorted octa­hedral geometry. The Co(III) ion is displaced...

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Detalles Bibliográficos
Autores principales: Wu, Qiong-Jie, Chen, Xiao-Hua, Jiang, Jiang, Cai, Bi-Qiong, Xie, Yong-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052150/
https://www.ncbi.nlm.nih.gov/pubmed/21522234
http://dx.doi.org/10.1107/S1600536811003321
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author Wu, Qiong-Jie
Chen, Xiao-Hua
Jiang, Jiang
Cai, Bi-Qiong
Xie, Yong-Ping
author_facet Wu, Qiong-Jie
Chen, Xiao-Hua
Jiang, Jiang
Cai, Bi-Qiong
Xie, Yong-Ping
author_sort Wu, Qiong-Jie
collection PubMed
description In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl­pyridine ligand and one Cl atom, forming a distorted octa­hedral geometry. The Co(III) ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom.
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spelling pubmed-30521502011-04-26 Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III) Wu, Qiong-Jie Chen, Xiao-Hua Jiang, Jiang Cai, Bi-Qiong Xie, Yong-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(15)H(12)N(3)O(4))(2)Cl(C(6)H(7)N)], the Co(III) ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methyl­pyridine ligand and one Cl atom, forming a distorted octa­hedral geometry. The Co(III) ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom. International Union of Crystallography 2011-02-02 /pmc/articles/PMC3052150/ /pubmed/21522234 http://dx.doi.org/10.1107/S1600536811003321 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Qiong-Jie
Chen, Xiao-Hua
Jiang, Jiang
Cai, Bi-Qiong
Xie, Yong-Ping
Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title_full Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title_fullStr Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title_full_unstemmed Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title_short Chloridobis[N′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) O,N′](4-methyl­pyridine-κN)cobalt(III)
title_sort chloridobis[n′-(2-meth­oxy­benzyl­idene)-4-nitro­benzohydrazidato-κ(2) o,n′](4-methyl­pyridine-κn)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052150/
https://www.ncbi.nlm.nih.gov/pubmed/21522234
http://dx.doi.org/10.1107/S1600536811003321
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