Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate

In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052153/
https://www.ncbi.nlm.nih.gov/pubmed/21522265
http://dx.doi.org/10.1107/S1600536811004892
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O—H⋯Cl hydrogen bonds link the complex mol­ecules and the uncoordinated water mol­ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C—H⋯O and C—H⋯Cl inter­actions.
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spelling pubmed-30521532011-04-26 Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O—H⋯Cl hydrogen bonds link the complex mol­ecules and the uncoordinated water mol­ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C—H⋯O and C—H⋯Cl inter­actions. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052153/ /pubmed/21522265 http://dx.doi.org/10.1107/S1600536811004892 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title_full Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title_fullStr Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title_full_unstemmed Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title_short Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}copper(II) monohydrate
title_sort dichlorido{2-(morpholin-4-yl)-n-[1-(pyridin-2-yl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052153/
https://www.ncbi.nlm.nih.gov/pubmed/21522265
http://dx.doi.org/10.1107/S1600536811004892
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AT khaledihamid dichlorido2morpholin4yln1pyridin2ylethylideneethanaminek3nnncopperiimonohydrate
AT mohdalihapipah dichlorido2morpholin4yln1pyridin2ylethylideneethanaminek3nnncopperiimonohydrate

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