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(2,2′-Bipyridine-κ(2) N,N′)bis(3-methoxybenzoato-κ(2) O (1),O (1′))copper(II) monohydrate
The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-methoxybenzoate ligands, a 2,2′-bipyridine (bipy) ligand and one uncoordinated water molecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate di...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052164/ https://www.ncbi.nlm.nih.gov/pubmed/21522281 http://dx.doi.org/10.1107/S1600536811005563 |
Sumario: | The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-methoxybenzoate ligands, a 2,2′-bipyridine (bipy) ligand and one uncoordinated water molecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate distorted octahedral geometry, with two N atoms from the bipy ligand [Cu—N = 1.9996 (16) Å] and four O atoms from two 3-methoxybenzoate ligands [Cu—O = 1.9551 (15) and 2.6016 (16) Å]. The molecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. |
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