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(2,2′-Bipyridine-κ(2) N,N′)bis­(3-meth­oxy­benzoato-κ(2) O (1),O (1′))copper(II) mono­hydrate

The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-meth­oxy­benzoate ligands, a 2,2′-bipyridine (bipy) ligand and one uncoordinated water mol­ecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate di...

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Detalles Bibliográficos
Autores principales: Lin, Ming-Hao, Zhou, Jing-Fan, Liu, Bin-Bin, Lin, Jian-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052164/
https://www.ncbi.nlm.nih.gov/pubmed/21522281
http://dx.doi.org/10.1107/S1600536811005563
Descripción
Sumario:The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-meth­oxy­benzoate ligands, a 2,2′-bipyridine (bipy) ligand and one uncoordinated water mol­ecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate distorted octa­hedral geometry, with two N atoms from the bipy ligand [Cu—N = 1.9996 (16) Å] and four O atoms from two 3-meth­oxy­benzoate ligands [Cu—O = 1.9551 (15) and 2.6016 (16) Å]. The mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network.