Nitro­furan­toin methanol monosolvate

The anti­biotic nitro­furan­toin {systematic name: (E)-1-[(5-nitro-2-fur­yl)methyl­idene­amino]­imidazolidine-2,4-dione} crys­tallizes as a methanol monosolvate, C(8)H(6)N(4)O(5)·CH(4)O. The nitro­furan­toin mol­ecule adopts a nearly planar conformation (r.m.s. deviation = 0.0344 Å). Hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Vangala, Venu R., Chow, Pui Shan, Tan, Reginald B. H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052167/
https://www.ncbi.nlm.nih.gov/pubmed/21522317
http://dx.doi.org/10.1107/S1600536811003679
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author Vangala, Venu R.
Chow, Pui Shan
Tan, Reginald B. H.
author_facet Vangala, Venu R.
Chow, Pui Shan
Tan, Reginald B. H.
author_sort Vangala, Venu R.
collection PubMed
description The anti­biotic nitro­furan­toin {systematic name: (E)-1-[(5-nitro-2-fur­yl)methyl­idene­amino]­imidazolidine-2,4-dione} crys­tallizes as a methanol monosolvate, C(8)H(6)N(4)O(5)·CH(4)O. The nitro­furan­toin mol­ecule adopts a nearly planar conformation (r.m.s. deviation = 0.0344 Å). Hydrogen bonds involve the co-operative N—H⋯O—H⋯O heterosynthons between the cyclic imide of nitro­furan­toin and methanol O—H groups. There are also C—H⋯O hydrogen bonds involving the nitro­furan­toin mol­ecules which support the key hydrogen-bonding synthon. The overall crystal packing is further assisted by weak C—H⋯O inter­actions, giving a herringbone pattern.
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spelling pubmed-30521672011-04-26 Nitro­furan­toin methanol monosolvate Vangala, Venu R. Chow, Pui Shan Tan, Reginald B. H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The anti­biotic nitro­furan­toin {systematic name: (E)-1-[(5-nitro-2-fur­yl)methyl­idene­amino]­imidazolidine-2,4-dione} crys­tallizes as a methanol monosolvate, C(8)H(6)N(4)O(5)·CH(4)O. The nitro­furan­toin mol­ecule adopts a nearly planar conformation (r.m.s. deviation = 0.0344 Å). Hydrogen bonds involve the co-operative N—H⋯O—H⋯O heterosynthons between the cyclic imide of nitro­furan­toin and methanol O—H groups. There are also C—H⋯O hydrogen bonds involving the nitro­furan­toin mol­ecules which support the key hydrogen-bonding synthon. The overall crystal packing is further assisted by weak C—H⋯O inter­actions, giving a herringbone pattern. International Union of Crystallography 2011-02-02 /pmc/articles/PMC3052167/ /pubmed/21522317 http://dx.doi.org/10.1107/S1600536811003679 Text en © Vangala et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vangala, Venu R.
Chow, Pui Shan
Tan, Reginald B. H.
Nitro­furan­toin methanol monosolvate
title Nitro­furan­toin methanol monosolvate
title_full Nitro­furan­toin methanol monosolvate
title_fullStr Nitro­furan­toin methanol monosolvate
title_full_unstemmed Nitro­furan­toin methanol monosolvate
title_short Nitro­furan­toin methanol monosolvate
title_sort nitro­furan­toin methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052167/
https://www.ncbi.nlm.nih.gov/pubmed/21522317
http://dx.doi.org/10.1107/S1600536811003679
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AT chowpuishan nitrofurantoinmethanolmonosolvate
AT tanreginaldbh nitrofurantoinmethanolmonosolvate

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