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3-{[6-(4-Chloro­phen­yl)imidazo[2,1-b][1,3,4]thia­diazol-2-yl]meth­yl}-1,2-benzoxazole

In the title compound, C(18)H(11)ClN(4)OS, the benzisoxazole and imidazothia­diazole rings are inclined at an angle of 23.81 (7)° with respect to each other. The imidazothia­diazole and chloro­phenyl rings make a dihedral angle of 27.34 (3)°. In the crystal, inter­molecular C—H⋯N inter­actions gener...

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Detalles Bibliográficos
Autores principales: Banu, Afshan, Ziaulla, Mohamed, Begum, Noor Shahina, Lamani, Ravi S., Khazi, I. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052169/
https://www.ncbi.nlm.nih.gov/pubmed/21522374
http://dx.doi.org/10.1107/S1600536811004582
Descripción
Sumario:In the title compound, C(18)H(11)ClN(4)OS, the benzisoxazole and imidazothia­diazole rings are inclined at an angle of 23.81 (7)° with respect to each other. The imidazothia­diazole and chloro­phenyl rings make a dihedral angle of 27.34 (3)°. In the crystal, inter­molecular C—H⋯N inter­actions generate a chain along the c axis and C—H⋯O inter­actions form centrosymmetric dimers resulting in an R (2) (2)(26) graph-set motif. Moreover, the C—H⋯N and S⋯N [3.206 (4) Å] inter­actions links the mol­ecules into R(7) ring motifs. The packing is further stabilized by π–π stacking inter­actions between the thia­diazole rings with a shortest centroid–centroid distance of 3.497 (3) Å. In addition, C—H⋯π inter­actions are observed in the crystal structure