Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls

Palladium supported on nickel ferrite (Pd/NiF(2)O(4)) was found to be a highly active catalyst for the Suzuki coupling reaction between various aryl halides and arylboronic acids. The reaction gave excellent yields (70–98%) under ligand free conditions in a 1:1 DMF/H(2)O solvent mixture, in short re...

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Detalles Bibliográficos
Autores principales: Borhade, Sanjay R, Waghmode, Suresh Babsaheb
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3063056/
https://www.ncbi.nlm.nih.gov/pubmed/21448255
http://dx.doi.org/10.3762/bjoc.7.41
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author Borhade, Sanjay R
Waghmode, Suresh Babsaheb
author_facet Borhade, Sanjay R
Waghmode, Suresh Babsaheb
author_sort Borhade, Sanjay R
collection PubMed
description Palladium supported on nickel ferrite (Pd/NiF(2)O(4)) was found to be a highly active catalyst for the Suzuki coupling reaction between various aryl halides and arylboronic acids. The reaction gave excellent yields (70–98%) under ligand free conditions in a 1:1 DMF/H(2)O solvent mixture, in short reaction times (10–60 min). The catalyst could be recovered easily by applying an external magnetic field. The polyaryls were similarly synthesized.
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spelling pubmed-30630562011-03-28 Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls Borhade, Sanjay R Waghmode, Suresh Babsaheb Beilstein J Org Chem Full Research Paper Palladium supported on nickel ferrite (Pd/NiF(2)O(4)) was found to be a highly active catalyst for the Suzuki coupling reaction between various aryl halides and arylboronic acids. The reaction gave excellent yields (70–98%) under ligand free conditions in a 1:1 DMF/H(2)O solvent mixture, in short reaction times (10–60 min). The catalyst could be recovered easily by applying an external magnetic field. The polyaryls were similarly synthesized. Beilstein-Institut 2011-03-15 /pmc/articles/PMC3063056/ /pubmed/21448255 http://dx.doi.org/10.3762/bjoc.7.41 Text en Copyright © 2011, Borhade and Waghmode https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Borhade, Sanjay R
Waghmode, Suresh Babsaheb
Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title_full Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title_fullStr Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title_full_unstemmed Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title_short Studies on Pd/NiFe(2)O(4) catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
title_sort studies on pd/nife(2)o(4) catalyzed ligand-free suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3063056/
https://www.ncbi.nlm.nih.gov/pubmed/21448255
http://dx.doi.org/10.3762/bjoc.7.41
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