1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methyl­sulfanyl]-1H-benzimidazole

In the title compound, C(29)H(24)N(4)O(4)S(3), the two N-tosyl­benzimidazolyl unit are connected through a —S—CH(2)— fragment, the dihedral angle between the benzimidazole rings being 76.09 (5)°. The methyl­thio group is disordered with respect to exchange of the S and C atoms in a 0.547 (4):0.453 (...

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Detalles Bibliográficos
Autores principales: N. Al-Mohammed, Nassir, Alias, Yatimah, Abdullah, Zanariah, Khaledi, Hamid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089064/
https://www.ncbi.nlm.nih.gov/pubmed/21754370
http://dx.doi.org/10.1107/S1600536811011822
Descripción
Sumario:In the title compound, C(29)H(24)N(4)O(4)S(3), the two N-tosyl­benzimidazolyl unit are connected through a —S—CH(2)— fragment, the dihedral angle between the benzimidazole rings being 76.09 (5)°. The methyl­thio group is disordered with respect to exchange of the S and C atoms in a 0.547 (4):0.453 (4) ratio. In the crystal, C—H⋯O and C—H⋯π inter­actions connect adjacent mol­ecules into infinite layers parallel to the ab plane. The crystal packing is further stabilized by a π–π inter­action [centroid–centroid separation = 3.5187 (4) Å].

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