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(2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV)
In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule. The axial sites are occupied by the O atoms of the methanol molecu...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089065/ https://www.ncbi.nlm.nih.gov/pubmed/21754275 http://dx.doi.org/10.1107/S1600536811011962 |
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author | Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Win, Yip-Foo |
collection | PubMed |
description | In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule. The axial sites are occupied by the O atoms of the methanol molecule and the carboxylate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitrobenzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the molecules are linked via intermolecular O—H⋯O and C—H⋯O hydrogen bonds into a column along the b axis. |
format | Text |
id | pubmed-3089065 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30890652011-07-13 (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxylate group, three phenyl rings and a methanol molecule. The axial sites are occupied by the O atoms of the methanol molecule and the carboxylate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitrobenzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the molecules are linked via intermolecular O—H⋯O and C—H⋯O hydrogen bonds into a column along the b axis. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089065/ /pubmed/21754275 http://dx.doi.org/10.1107/S1600536811011962 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Quah, Ching Kheng Fun, Hoong-Kun (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title | (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title_full | (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title_fullStr | (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title_full_unstemmed | (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title_short | (2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV) |
title_sort | (2-chloro-4-nitrobenzoato)(methanol)triphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089065/ https://www.ncbi.nlm.nih.gov/pubmed/21754275 http://dx.doi.org/10.1107/S1600536811011962 |
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