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(2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)

In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxyl­ate group, three phenyl rings and a methanol mol­ecule. The axial sites are occupied by the O atoms of the methanol mol­ecu...

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Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Ha, Sie-Tiong, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089065/
https://www.ncbi.nlm.nih.gov/pubmed/21754275
http://dx.doi.org/10.1107/S1600536811011962
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author Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxyl­ate group, three phenyl rings and a methanol mol­ecule. The axial sites are occupied by the O atoms of the methanol mol­ecule and the carboxyl­ate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitro­benzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the mol­ecules are linked via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds into a column along the b axis.
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spelling pubmed-30890652011-07-13 (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV) Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal–bipyramidal environment, formed by a monodentate carboxyl­ate group, three phenyl rings and a methanol mol­ecule. The axial sites are occupied by the O atoms of the methanol mol­ecule and the carboxyl­ate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitro­benzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the mol­ecules are linked via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds into a column along the b axis. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089065/ /pubmed/21754275 http://dx.doi.org/10.1107/S1600536811011962 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Quah, Ching Kheng
Fun, Hoong-Kun
(2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title_full (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title_fullStr (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title_full_unstemmed (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title_short (2-Chloro-4-nitro­benzoato)(methanol)triphenyl­tin(IV)
title_sort (2-chloro-4-nitro­benzoato)(methanol)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089065/
https://www.ncbi.nlm.nih.gov/pubmed/21754275
http://dx.doi.org/10.1107/S1600536811011962
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