N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate

The mol­ecular structure of the title compound, C(26)H(32)N(3)S(+)·PF(6) (−), shows a protonated guanidyl group bridged by an ethyl­ene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—C(gua) bonds. The N—C—C—S group shows a folded nonplan...

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Detalles Bibliográficos
Autores principales: Neuba, Adam, Flörke, Ulrich, Henkel, Gerald
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089070/
https://www.ncbi.nlm.nih.gov/pubmed/21754533
http://dx.doi.org/10.1107/S1600536811014929
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author Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
author_facet Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
author_sort Neuba, Adam
collection PubMed
description The mol­ecular structure of the title compound, C(26)H(32)N(3)S(+)·PF(6) (−), shows a protonated guanidyl group bridged by an ethyl­ene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—C(gua) bonds. The N—C—C—S group shows a folded nonplanar conformation with a torsion angle of 158.4 (1)°. In the crystal, the cation and anion are linked by an N—H⋯F inter­action.
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spelling pubmed-30890702011-07-13 N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate Neuba, Adam Flörke, Ulrich Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(26)H(32)N(3)S(+)·PF(6) (−), shows a protonated guanidyl group bridged by an ethyl­ene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—C(gua) bonds. The N—C—C—S group shows a folded nonplanar conformation with a torsion angle of 158.4 (1)°. In the crystal, the cation and anion are linked by an N—H⋯F inter­action. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089070/ /pubmed/21754533 http://dx.doi.org/10.1107/S1600536811014929 Text en © Neuba et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title_full N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title_fullStr N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title_full_unstemmed N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title_short N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
title_sort n-[bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089070/
https://www.ncbi.nlm.nih.gov/pubmed/21754533
http://dx.doi.org/10.1107/S1600536811014929
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AT henkelgerald nbisdimethylaminomethylidene2triphenylmethylsulfanylethanaminiumhexafluorophosphate

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