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(2E)-2-[2-(Cyclohexylcarbamothioyl)hydrazinylidene]propanoic acid
In the title thiourea derivative, C(10)H(17)N(3)O(2)S, the carboxyl group and the least-squares plane through the cyclohexyl ring are twisted out of the plane through the central CN(3)S residue; the respective dihedral angles are 7.18 (8) and 62.29 (4)°. The conformation about the azomethine bond...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089072/ https://www.ncbi.nlm.nih.gov/pubmed/21754495 http://dx.doi.org/10.1107/S1600536811014449 |
Sumario: | In the title thiourea derivative, C(10)H(17)N(3)O(2)S, the carboxyl group and the least-squares plane through the cyclohexyl ring are twisted out of the plane through the central CN(3)S residue; the respective dihedral angles are 7.18 (8) and 62.29 (4)°. The conformation about the azomethine bond [1.275 (2) Å] is E. The NH groups are anti, with one forming an intramolecular N—H⋯N hydrogen bond. The main feature of the crystal structure is the formation of linear supramolecular chains along [110] mediated by alternating pairs of O—H⋯O and pairs of N—H⋯S hydrogen bonds. |
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