Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate

In the title compound, C(26)H(21)F(6)NO(5), the dihedral angle between the cyclo­propane ring plane and the vinyl group plane is 79.3 (3)°. The dihedral angle between the benzene and phenyl ring planes in the phen­oxy­benzyl group is 82.7 (1)°. In the crystal structure, weak inter­molecular C—H⋯π in...

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Detalles Bibliográficos
Autores principales: Yang, Hojin, Kim, Tae Ho, Park, Ki-Min, Kim, Jineun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089073/
https://www.ncbi.nlm.nih.gov/pubmed/21754558
http://dx.doi.org/10.1107/S1600536811014760
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author Yang, Hojin
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
author_facet Yang, Hojin
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
author_sort Yang, Hojin
collection PubMed
description In the title compound, C(26)H(21)F(6)NO(5), the dihedral angle between the cyclo­propane ring plane and the vinyl group plane is 79.3 (3)°. The dihedral angle between the benzene and phenyl ring planes in the phen­oxy­benzyl group is 82.7 (1)°. In the crystal structure, weak inter­molecular C—H⋯π inter­actions and C—H⋯F hydrogen bonds contribute to the stabilization of the packing.
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spelling pubmed-30890732011-07-13 Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate Yang, Hojin Kim, Tae Ho Park, Ki-Min Kim, Jineun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(21)F(6)NO(5), the dihedral angle between the cyclo­propane ring plane and the vinyl group plane is 79.3 (3)°. The dihedral angle between the benzene and phenyl ring planes in the phen­oxy­benzyl group is 82.7 (1)°. In the crystal structure, weak inter­molecular C—H⋯π inter­actions and C—H⋯F hydrogen bonds contribute to the stabilization of the packing. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089073/ /pubmed/21754558 http://dx.doi.org/10.1107/S1600536811014760 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Hojin
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title_full Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title_fullStr Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title_full_unstemmed Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title_short Acrinathrin: (S)-cyano­(3-phen­oxy­phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
title_sort acrinathrin: (s)-cyano­(3-phen­oxy­phenyl)methyl (z)-(1r,3s)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro­methyl)eth­oxy­carbon­yl]vin­yl}cyclo­propane-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089073/
https://www.ncbi.nlm.nih.gov/pubmed/21754558
http://dx.doi.org/10.1107/S1600536811014760
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AT kimtaeho acrinathrinscyano3phenoxyphenylmethylz1r3s22dimethyl32222trifluoro1trifluoromethylethoxycarbonylvinylcyclopropane1carboxylate
AT parkkimin acrinathrinscyano3phenoxyphenylmethylz1r3s22dimethyl32222trifluoro1trifluoromethylethoxycarbonylvinylcyclopropane1carboxylate
AT kimjineun acrinathrinscyano3phenoxyphenylmethylz1r3s22dimethyl32222trifluoro1trifluoromethylethoxycarbonylvinylcyclopropane1carboxylate

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