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(Methanol-κO)(2-methyl-3,5-dinitro­benzoato-κO)triphenyl­tin(IV)

In the title complex, [Sn(C(6)H(5))(3)(C(8)H(5)N(2)O(6))(CH(3)OH)], the Sn(IV) ion is coordinated in a slightly distorted trigonal–bipyramidal geometry by three phenyl ligands in the equatorial plane and by a 2-methyl-3,5-dinitro­benzene­carboxyl­ato ligand and a methanol ligand at the apical sites....

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Detalles Bibliográficos
Autores principales: Danish, Muhammad, Ghafoor, Sabiha, Ahmad, Nazir, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089075/
https://www.ncbi.nlm.nih.gov/pubmed/21754262
http://dx.doi.org/10.1107/S1600536811011184
Descripción
Sumario:In the title complex, [Sn(C(6)H(5))(3)(C(8)H(5)N(2)O(6))(CH(3)OH)], the Sn(IV) ion is coordinated in a slightly distorted trigonal–bipyramidal geometry by three phenyl ligands in the equatorial plane and by a 2-methyl-3,5-dinitro­benzene­carboxyl­ato ligand and a methanol ligand at the apical sites. In the crystal, complex mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds, forming chains along [100].