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Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]isopropylamine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089087/ https://www.ncbi.nlm.nih.gov/pubmed/21754326 http://dx.doi.org/10.1107/S1600536811013936 |
Sumario: | In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C—H⋯O interaction. The crystal structure is further stabilized through two intermolecular C—H⋯π interactions. |
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