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Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate

In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089087/
https://www.ncbi.nlm.nih.gov/pubmed/21754326
http://dx.doi.org/10.1107/S1600536811013936
Descripción
Sumario:In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol­ecules form centrosymmetric dimers due to an inter­molecular C—H⋯O inter­action. The crystal structure is further stabilized through two inter­molecular C—H⋯π inter­actions.