Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate

In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined...

Descripción completa

Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089087/
https://www.ncbi.nlm.nih.gov/pubmed/21754326
http://dx.doi.org/10.1107/S1600536811013936
_version_ 1782202974558224384
author Chiririwa, Haleden
Meijboom, Reinout
Omondi, Bernard
author_facet Chiririwa, Haleden
Meijboom, Reinout
Omondi, Bernard
author_sort Chiririwa, Haleden
collection PubMed
description In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol­ecules form centrosymmetric dimers due to an inter­molecular C—H⋯O inter­action. The crystal structure is further stabilized through two inter­molecular C—H⋯π inter­actions.
format Text
id pubmed-3089087
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30890872011-07-13 Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate Chiririwa, Haleden Meijboom, Reinout Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(−) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol­ecules form centrosymmetric dimers due to an inter­molecular C—H⋯O inter­action. The crystal structure is further stabilized through two inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089087/ /pubmed/21754326 http://dx.doi.org/10.1107/S1600536811013936 Text en © Chiririwa et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
Omondi, Bernard
Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title_full Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title_fullStr Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title_full_unstemmed Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title_short Dichlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) N,P}palladium(II) dimethyl sulfoxide monosolvate
title_sort dichlorido{n-[2-(diphenyl­phosphan­yl)benzyl­idene]isopropyl­amine-κ(2) n,p}palladium(ii) dimethyl sulfoxide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089087/
https://www.ncbi.nlm.nih.gov/pubmed/21754326
http://dx.doi.org/10.1107/S1600536811013936
work_keys_str_mv AT chiririwahaleden dichloridon2diphenylphosphanylbenzylideneisopropylaminek2nppalladiumiidimethylsulfoxidemonosolvate
AT meijboomreinout dichloridon2diphenylphosphanylbenzylideneisopropylaminek2nppalladiumiidimethylsulfoxidemonosolvate
AT omondibernard dichloridon2diphenylphosphanylbenzylideneisopropylaminek2nppalladiumiidimethylsulfoxidemonosolvate

Ejemplares similares