6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine

In the title compound, C(12)H(13)N(3)O(6), the dihydro­pyran ring adopts a near screw-boat conformation. The dihedral angle between the mean planes of the benzene and dihydro­pyran rings is 6.35 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) motif, which stabilizes the mol­ecular con...

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Detalles Bibliográficos
Autores principales: Muthukumaran, J., Parthiban, A., Manivel, P., Rao, H. Surya Prakash, Krishna, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089089/
https://www.ncbi.nlm.nih.gov/pubmed/21754559
http://dx.doi.org/10.1107/S1600536811015595
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author Muthukumaran, J.
Parthiban, A.
Manivel, P.
Rao, H. Surya Prakash
Krishna, R.
author_facet Muthukumaran, J.
Parthiban, A.
Manivel, P.
Rao, H. Surya Prakash
Krishna, R.
author_sort Muthukumaran, J.
collection PubMed
description In the title compound, C(12)H(13)N(3)O(6), the dihydro­pyran ring adopts a near screw-boat conformation. The dihedral angle between the mean planes of the benzene and dihydro­pyran rings is 6.35 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) motif, which stabilizes the mol­ecular conformation. In the crystal, weak inter­molecular C—H⋯O, N—H⋯O and C—H⋯π hydrogen bonds contribute to the stabilization of the packing.
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spelling pubmed-30890892011-07-13 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine Muthukumaran, J. Parthiban, A. Manivel, P. Rao, H. Surya Prakash Krishna, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(13)N(3)O(6), the dihydro­pyran ring adopts a near screw-boat conformation. The dihedral angle between the mean planes of the benzene and dihydro­pyran rings is 6.35 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) motif, which stabilizes the mol­ecular conformation. In the crystal, weak inter­molecular C—H⋯O, N—H⋯O and C—H⋯π hydrogen bonds contribute to the stabilization of the packing. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089089/ /pubmed/21754559 http://dx.doi.org/10.1107/S1600536811015595 Text en © Muthukumaran et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Muthukumaran, J.
Parthiban, A.
Manivel, P.
Rao, H. Surya Prakash
Krishna, R.
6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title_full 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title_fullStr 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title_full_unstemmed 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title_short 6-Meth­oxy-N-methyl-3-nitro-4-nitro­methyl-4H-chromen-2-amine
title_sort 6-meth­oxy-n-methyl-3-nitro-4-nitro­methyl-4h-chromen-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089089/
https://www.ncbi.nlm.nih.gov/pubmed/21754559
http://dx.doi.org/10.1107/S1600536811015595
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