trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc

In the title compound, [Zn(C(10)H(10)NO(3))(2)(H(2)O)(4)], the Zn(II) atom lies on a crystallographic inversion center and is six-coordinated by two monodentate trans-related 2-(N-acetyl­amino)-5-methyl­benzoato ligands and four water mol­ecules, giving a slightly distorted octa­hedral geometry. The...

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Detalles Bibliográficos
Autores principales: Huang, Jin-Feng, Zheng, Jian-You, Dai, Yu-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089096/
https://www.ncbi.nlm.nih.gov/pubmed/21754280
http://dx.doi.org/10.1107/S1600536811012013
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author Huang, Jin-Feng
Zheng, Jian-You
Dai, Yu-Mei
author_facet Huang, Jin-Feng
Zheng, Jian-You
Dai, Yu-Mei
author_sort Huang, Jin-Feng
collection PubMed
description In the title compound, [Zn(C(10)H(10)NO(3))(2)(H(2)O)(4)], the Zn(II) atom lies on a crystallographic inversion center and is six-coordinated by two monodentate trans-related 2-(N-acetyl­amino)-5-methyl­benzoato ligands and four water mol­ecules, giving a slightly distorted octa­hedral geometry. There are two intra­molecular hydrogen bonds [amine N—H⋯O(carbox­yl) and water O—H⋯O(carbox­yl)], while extensive inter­molecular water O—H⋯O hydrogen-bonding inter­actions extend the complex units into a two-dimensional network structure along (100).
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spelling pubmed-30890962011-07-13 trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc Huang, Jin-Feng Zheng, Jian-You Dai, Yu-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(10)H(10)NO(3))(2)(H(2)O)(4)], the Zn(II) atom lies on a crystallographic inversion center and is six-coordinated by two monodentate trans-related 2-(N-acetyl­amino)-5-methyl­benzoato ligands and four water mol­ecules, giving a slightly distorted octa­hedral geometry. There are two intra­molecular hydrogen bonds [amine N—H⋯O(carbox­yl) and water O—H⋯O(carbox­yl)], while extensive inter­molecular water O—H⋯O hydrogen-bonding inter­actions extend the complex units into a two-dimensional network structure along (100). International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089096/ /pubmed/21754280 http://dx.doi.org/10.1107/S1600536811012013 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Jin-Feng
Zheng, Jian-You
Dai, Yu-Mei
trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title_full trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title_fullStr trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title_full_unstemmed trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title_short trans-Bis(2-acet­amido-5-methyl­benzoato-κO (1))tetra­aqua­zinc
title_sort trans-bis(2-acet­amido-5-methyl­benzoato-κo (1))tetra­aqua­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089096/
https://www.ncbi.nlm.nih.gov/pubmed/21754280
http://dx.doi.org/10.1107/S1600536811012013
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