Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate

The title compound, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(10)CO(2)](2)·2H(2)O, consists of one cationic copper(II) complex, two dodeca­noate anions and two water solvent mol­ecules. The Cu(II) atom is located on an inversion center and is chelated by the four aza N atoms of the neutral 1,4,8,1...

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Detalles Bibliográficos
Autores principales: Ahmad Tajidi, Nur Syamimi, Abdullah, Norbani, Arifin, Zainudin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089101/
https://www.ncbi.nlm.nih.gov/pubmed/21754311
http://dx.doi.org/10.1107/S1600536811012773
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author Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
author_facet Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
author_sort Ahmad Tajidi, Nur Syamimi
collection PubMed
description The title compound, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(10)CO(2)](2)·2H(2)O, consists of one cationic copper(II) complex, two dodeca­noate anions and two water solvent mol­ecules. The Cu(II) atom is located on an inversion center and is chelated by the four aza N atoms of the neutral 1,4,8,11-tetra­aza­cyclo­tetra­decane (cyclam) ligand and by two water mol­ecules in axial positions, giving an octa­hedral coordination geometry, distorted as a consequence of the Jahn–Teller effect. The uncoordinated water mol­ecules link the complex cations and the dodeca­noate counter-ions through O—H⋯O hydrogen bonding, forming a layer structure parallel to (001). Inter­molecular N—H⋯O inter­actions also occur.
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spelling pubmed-30891012011-07-13 Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate Ahmad Tajidi, Nur Syamimi Abdullah, Norbani Arifin, Zainudin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(10)CO(2)](2)·2H(2)O, consists of one cationic copper(II) complex, two dodeca­noate anions and two water solvent mol­ecules. The Cu(II) atom is located on an inversion center and is chelated by the four aza N atoms of the neutral 1,4,8,11-tetra­aza­cyclo­tetra­decane (cyclam) ligand and by two water mol­ecules in axial positions, giving an octa­hedral coordination geometry, distorted as a consequence of the Jahn–Teller effect. The uncoordinated water mol­ecules link the complex cations and the dodeca­noate counter-ions through O—H⋯O hydrogen bonding, forming a layer structure parallel to (001). Inter­molecular N—H⋯O inter­actions also occur. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089101/ /pubmed/21754311 http://dx.doi.org/10.1107/S1600536811012773 Text en © Ahmad Tajidi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title_full Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title_fullStr Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title_full_unstemmed Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title_short Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) didodeca­noate dihydrate
title_sort diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) n (1),n (4),n (8),n (11))copper(ii) didodeca­noate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089101/
https://www.ncbi.nlm.nih.gov/pubmed/21754311
http://dx.doi.org/10.1107/S1600536811012773
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