2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)

In the title compound, C(5)H(8)N(3) (+)·C(24)H(20)B(−)·C(20)H(18)N(6), the 1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene mol­ecule is essentially planar (r.m.s. deviation = 0.0045 Å) and aligned in nearly coplanar manner with the 2,6-diamino­pyridinium ion, making a dihedral angle of 5.19 (5)°...

Descripción completa

Detalles Bibliográficos
Autores principales: Mudraboyina, Bhanu P., Wang, Hong-Bo, Newbury, Roaxanne, Wisner, James A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089105/
https://www.ncbi.nlm.nih.gov/pubmed/21754520
http://dx.doi.org/10.1107/S1600536811012943
_version_ 1782202978800762880
author Mudraboyina, Bhanu P.
Wang, Hong-Bo
Newbury, Roaxanne
Wisner, James A.
author_facet Mudraboyina, Bhanu P.
Wang, Hong-Bo
Newbury, Roaxanne
Wisner, James A.
author_sort Mudraboyina, Bhanu P.
collection PubMed
description In the title compound, C(5)H(8)N(3) (+)·C(24)H(20)B(−)·C(20)H(18)N(6), the 1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene mol­ecule is essentially planar (r.m.s. deviation = 0.0045 Å) and aligned in nearly coplanar manner with the 2,6-diamino­pyridinium ion, making a dihedral angle of 5.19 (5)°. The diamino­pyridine mol­ecule is protonated on the central pyridine N atom and the B atom bears the counter-charge. The amine groups of the diamino pyridinium cation form intra­molecular N—H⋯N hydrogen bonds, resulting in linear and bent inter­actions with the naphthyridine ring system.
format Text
id pubmed-3089105
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891052011-07-13 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1) Mudraboyina, Bhanu P. Wang, Hong-Bo Newbury, Roaxanne Wisner, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(8)N(3) (+)·C(24)H(20)B(−)·C(20)H(18)N(6), the 1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene mol­ecule is essentially planar (r.m.s. deviation = 0.0045 Å) and aligned in nearly coplanar manner with the 2,6-diamino­pyridinium ion, making a dihedral angle of 5.19 (5)°. The diamino­pyridine mol­ecule is protonated on the central pyridine N atom and the B atom bears the counter-charge. The amine groups of the diamino pyridinium cation form intra­molecular N—H⋯N hydrogen bonds, resulting in linear and bent inter­actions with the naphthyridine ring system. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089105/ /pubmed/21754520 http://dx.doi.org/10.1107/S1600536811012943 Text en © Mudraboyina et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mudraboyina, Bhanu P.
Wang, Hong-Bo
Newbury, Roaxanne
Wisner, James A.
2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title_full 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title_fullStr 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title_full_unstemmed 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title_short 2,6-Diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
title_sort 2,6-diamino­pyridinium tetra­phenyl­borate–1,2-bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089105/
https://www.ncbi.nlm.nih.gov/pubmed/21754520
http://dx.doi.org/10.1107/S1600536811012943
work_keys_str_mv AT mudraboyinabhanup 26diaminopyridiniumtetraphenylborate12bis57dimethyl18naphthyridin2yldiazene11
AT wanghongbo 26diaminopyridiniumtetraphenylborate12bis57dimethyl18naphthyridin2yldiazene11
AT newburyroaxanne 26diaminopyridiniumtetraphenylborate12bis57dimethyl18naphthyridin2yldiazene11
AT wisnerjamesa 26diaminopyridiniumtetraphenylborate12bis57dimethyl18naphthyridin2yldiazene11

Ejemplares similares