[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination,...

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Detalles Bibliográficos
Autores principales: Sung, Hui-Ling, Her, Tze-Min, Su, Wen-Hsien, Cheng, Chin-Pao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089106/
https://www.ncbi.nlm.nih.gov/pubmed/21754349
http://dx.doi.org/10.1107/S1600536811015121
Descripción
Sumario:Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru—P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

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