[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination,...

Descripción completa

Detalles Bibliográficos
Autores principales: Sung, Hui-Ling, Her, Tze-Min, Su, Wen-Hsien, Cheng, Chin-Pao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089106/
https://www.ncbi.nlm.nih.gov/pubmed/21754349
http://dx.doi.org/10.1107/S1600536811015121
_version_ 1782202979055566848
author Sung, Hui-Ling
Her, Tze-Min
Su, Wen-Hsien
Cheng, Chin-Pao
author_facet Sung, Hui-Ling
Her, Tze-Min
Su, Wen-Hsien
Cheng, Chin-Pao
author_sort Sung, Hui-Ling
collection PubMed
description Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru—P bond lengths are 2.2502 (9) and 2.2968 (8) Å.
format Text
id pubmed-3089106
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891062011-07-13 [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II) Sung, Hui-Ling Her, Tze-Min Su, Wen-Hsien Cheng, Chin-Pao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis­(diphenyl­phosphan­yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru—P bond lengths are 2.2502 (9) and 2.2968 (8) Å. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089106/ /pubmed/21754349 http://dx.doi.org/10.1107/S1600536811015121 Text en © Sung et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sung, Hui-Ling
Her, Tze-Min
Su, Wen-Hsien
Cheng, Chin-Pao
[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title_full [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title_fullStr [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title_full_unstemmed [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title_short [1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]chlorido(η(5)-inden­yl)ruthenium(II)
title_sort [1,4-bis(diphenyl­phosphan­yl)butane-κ(2) p,p′]chlorido(η(5)-inden­yl)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089106/
https://www.ncbi.nlm.nih.gov/pubmed/21754349
http://dx.doi.org/10.1107/S1600536811015121
work_keys_str_mv AT sunghuiling 14bisdiphenylphosphanylbutanek2ppchloridoē5indenylrutheniumii
AT hertzemin 14bisdiphenylphosphanylbutanek2ppchloridoē5indenylrutheniumii
AT suwenhsien 14bisdiphenylphosphanylbutanek2ppchloridoē5indenylrutheniumii
AT chengchinpao 14bisdiphenylphosphanylbutanek2ppchloridoē5indenylrutheniumii

Ejemplares similares