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Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate

In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa­hedral coordination environment. The lengths o...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Kou, Fan, Jia, Fei, Yuan, Jingkun, Liu, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089108/
https://www.ncbi.nlm.nih.gov/pubmed/21754353
http://dx.doi.org/10.1107/S160053681101525X
Descripción
Sumario:In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa­hedral coordination environment. The lengths of the chemically equivalent Cd—O bonds [2.4850 (16) and 2.5488 (16)Å] are signiificantly different. One of the picrate anions is disordered over two sets of sites, with refined occupancies of 0.504 (15) and 0.496 (15). A 0.5-occupancy acetonitrile solvent mol­ecule is disordered over two sites with equal occupancies. The H atoms of a 0.25-occupancy solvent water mol­ecule were neither located nor included in the refinement.