Cargando…
Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octahedral coordination environment. The lengths o...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089108/ https://www.ncbi.nlm.nih.gov/pubmed/21754353 http://dx.doi.org/10.1107/S160053681101525X |
_version_ | 1782202979542106112 |
---|---|
author | Wu, Huilu Kou, Fan Jia, Fei Yuan, Jingkun Liu, Bin |
author_facet | Wu, Huilu Kou, Fan Jia, Fei Yuan, Jingkun Liu, Bin |
author_sort | Wu, Huilu |
collection | PubMed |
description | In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octahedral coordination environment. The lengths of the chemically equivalent Cd—O bonds [2.4850 (16) and 2.5488 (16)Å] are signiificantly different. One of the picrate anions is disordered over two sets of sites, with refined occupancies of 0.504 (15) and 0.496 (15). A 0.5-occupancy acetonitrile solvent molecule is disordered over two sites with equal occupancies. The H atoms of a 0.25-occupancy solvent water molecule were neither located nor included in the refinement. |
format | Text |
id | pubmed-3089108 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891082011-07-13 Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate Wu, Huilu Kou, Fan Jia, Fei Yuan, Jingkun Liu, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octahedral coordination environment. The lengths of the chemically equivalent Cd—O bonds [2.4850 (16) and 2.5488 (16)Å] are signiificantly different. One of the picrate anions is disordered over two sets of sites, with refined occupancies of 0.504 (15) and 0.496 (15). A 0.5-occupancy acetonitrile solvent molecule is disordered over two sites with equal occupancies. The H atoms of a 0.25-occupancy solvent water molecule were neither located nor included in the refinement. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089108/ /pubmed/21754353 http://dx.doi.org/10.1107/S160053681101525X Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Huilu Kou, Fan Jia, Fei Yuan, Jingkun Liu, Bin Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title | Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title_full | Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title_fullStr | Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title_full_unstemmed | Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title_short | Bis[1,3-bis(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
title_sort | bis[1,3-bis(1-methyl-1h-benzimidazol-2-yl)-2-oxapropane]cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089108/ https://www.ncbi.nlm.nih.gov/pubmed/21754353 http://dx.doi.org/10.1107/S160053681101525X |
work_keys_str_mv | AT wuhuilu bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate AT koufan bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate AT jiafei bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate AT yuanjingkun bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate AT liubin bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate |