Cargando…

Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate

In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa­hedral coordination environment. The lengths o...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Huilu, Kou, Fan, Jia, Fei, Yuan, Jingkun, Liu, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089108/
https://www.ncbi.nlm.nih.gov/pubmed/21754353
http://dx.doi.org/10.1107/S160053681101525X
_version_ 1782202979542106112
author Wu, Huilu
Kou, Fan
Jia, Fei
Yuan, Jingkun
Liu, Bin
author_facet Wu, Huilu
Kou, Fan
Jia, Fei
Yuan, Jingkun
Liu, Bin
author_sort Wu, Huilu
collection PubMed
description In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa­hedral coordination environment. The lengths of the chemically equivalent Cd—O bonds [2.4850 (16) and 2.5488 (16)Å] are signiificantly different. One of the picrate anions is disordered over two sets of sites, with refined occupancies of 0.504 (15) and 0.496 (15). A 0.5-occupancy acetonitrile solvent mol­ecule is disordered over two sites with equal occupancies. The H atoms of a 0.25-occupancy solvent water mol­ecule were neither located nor included in the refinement.
format Text
id pubmed-3089108
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891082011-07-13 Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate Wu, Huilu Kou, Fan Jia, Fei Yuan, Jingkun Liu, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(18)H(18)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·1.5CH(3)CN·0.25H(2)O, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa­hedral coordination environment. The lengths of the chemically equivalent Cd—O bonds [2.4850 (16) and 2.5488 (16)Å] are signiificantly different. One of the picrate anions is disordered over two sets of sites, with refined occupancies of 0.504 (15) and 0.496 (15). A 0.5-occupancy acetonitrile solvent mol­ecule is disordered over two sites with equal occupancies. The H atoms of a 0.25-occupancy solvent water mol­ecule were neither located nor included in the refinement. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089108/ /pubmed/21754353 http://dx.doi.org/10.1107/S160053681101525X Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Huilu
Kou, Fan
Jia, Fei
Yuan, Jingkun
Liu, Bin
Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title_full Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title_fullStr Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title_full_unstemmed Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title_short Bis[1,3-bis­(1-methyl-1H-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
title_sort bis[1,3-bis­(1-methyl-1h-benzimidazol-2-yl)-2-oxapropane]­cadmium dipicrate acetonitrile sesquisolvate 0.25-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089108/
https://www.ncbi.nlm.nih.gov/pubmed/21754353
http://dx.doi.org/10.1107/S160053681101525X
work_keys_str_mv AT wuhuilu bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate
AT koufan bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate
AT jiafei bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate
AT yuanjingkun bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate
AT liubin bis13bis1methyl1hbenzimidazol2yl2oxapropanecadmiumdipicrateacetonitrilesesquisolvate025hydrate