2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole

The asymmetric unit of the title compound, C(15)H(15)N(3), contains two crystallographically independent mol­ecules with very similar geometries. The imidazole and indenyl planes are approximately orthogonal, making dihedral angles of 88.21 (9) and 83.08 (9)%deg; in the two independent molecules. In...

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Detalles Bibliográficos
Autores principales: Li, Zhao, Tian, Chong, Nie, Wanli, Borzov, Maxim V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089109/
https://www.ncbi.nlm.nih.gov/pubmed/21754472
http://dx.doi.org/10.1107/S1600536811013286
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author Li, Zhao
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
author_facet Li, Zhao
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
author_sort Li, Zhao
collection PubMed
description The asymmetric unit of the title compound, C(15)H(15)N(3), contains two crystallographically independent mol­ecules with very similar geometries. The imidazole and indenyl planes are approximately orthogonal, making dihedral angles of 88.21 (9) and 83.08 (9)%deg; in the two independent molecules. In the crystal, the imidazole units are linked by N—H⋯N hydrogen bonds into chains parallel to the 101) plane stretched in the diagonal direction [translation vector ([Image: see text],1,0); C(4) motif]. Within a chain, there are two types of symmetrically non-equivalent alternating H-bonds which slightly differ in their parameters.
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spelling pubmed-30891092011-07-13 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole Li, Zhao Tian, Chong Nie, Wanli Borzov, Maxim V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(15)N(3), contains two crystallographically independent mol­ecules with very similar geometries. The imidazole and indenyl planes are approximately orthogonal, making dihedral angles of 88.21 (9) and 83.08 (9)%deg; in the two independent molecules. In the crystal, the imidazole units are linked by N—H⋯N hydrogen bonds into chains parallel to the 101) plane stretched in the diagonal direction [translation vector ([Image: see text],1,0); C(4) motif]. Within a chain, there are two types of symmetrically non-equivalent alternating H-bonds which slightly differ in their parameters. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089109/ /pubmed/21754472 http://dx.doi.org/10.1107/S1600536811013286 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhao
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title_full 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title_fullStr 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title_full_unstemmed 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title_short 2-{(E)-N-[2-(1H-Inden-3-yl)eth­yl]imino­meth­yl}-1H-imidazole
title_sort 2-{(e)-n-[2-(1h-inden-3-yl)eth­yl]imino­meth­yl}-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089109/
https://www.ncbi.nlm.nih.gov/pubmed/21754472
http://dx.doi.org/10.1107/S1600536811013286
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AT tianchong 2en21hinden3ylethyliminomethyl1himidazole
AT niewanli 2en21hinden3ylethyliminomethyl1himidazole
AT borzovmaximv 2en21hinden3ylethyliminomethyl1himidazole

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