Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]

In the mixed-valence Cu(I)/Cu(II) coordination polymer, [Cu(2)Cl(3)(C(20)H(14)N(4))](n), the two Cu atoms are bridged to a pair of Cl atoms across a centre of inversion. The monovalent metal atoms is coordinated by a pyridine N atom as well as by three Cl atoms in a tetra­hedral CuNCl(3) geometry. T...

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Detalles Bibliográficos
Autor principal: Zhu, Chao-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089113/
https://www.ncbi.nlm.nih.gov/pubmed/21754347
http://dx.doi.org/10.1107/S1600536811014759
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author Zhu, Chao-Ying
author_facet Zhu, Chao-Ying
author_sort Zhu, Chao-Ying
collection PubMed
description In the mixed-valence Cu(I)/Cu(II) coordination polymer, [Cu(2)Cl(3)(C(20)H(14)N(4))](n), the two Cu atoms are bridged to a pair of Cl atoms across a centre of inversion. The monovalent metal atoms is coordinated by a pyridine N atom as well as by three Cl atoms in a tetra­hedral CuNCl(3) geometry. The divalent metal atom is N,N′,N′′-chelated by the heterocycle, and it exists in a square-pyramidal CuN(3)Cl(2) geometry; the apical site is occupied by the second bridging Cl atom. The bridging modes of the Cl atoms and the heterocycle give rise to the formation of a layered arrangement parallel to (001).
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spelling pubmed-30891132011-07-13 Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)] Zhu, Chao-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mixed-valence Cu(I)/Cu(II) coordination polymer, [Cu(2)Cl(3)(C(20)H(14)N(4))](n), the two Cu atoms are bridged to a pair of Cl atoms across a centre of inversion. The monovalent metal atoms is coordinated by a pyridine N atom as well as by three Cl atoms in a tetra­hedral CuNCl(3) geometry. The divalent metal atom is N,N′,N′′-chelated by the heterocycle, and it exists in a square-pyramidal CuN(3)Cl(2) geometry; the apical site is occupied by the second bridging Cl atom. The bridging modes of the Cl atoms and the heterocycle give rise to the formation of a layered arrangement parallel to (001). International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089113/ /pubmed/21754347 http://dx.doi.org/10.1107/S1600536811014759 Text en © Chao-Ying Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Chao-Ying
Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title_full Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title_fullStr Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title_full_unstemmed Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title_short Poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(I)copper(II)]
title_sort poly[μ(2)-chlorido-dichlorido[μ(2)-4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­copper(i)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089113/
https://www.ncbi.nlm.nih.gov/pubmed/21754347
http://dx.doi.org/10.1107/S1600536811014759
work_keys_str_mv AT zhuchaoying polym2chloridodichloridom244pyridyl2262terpyridinecoppericopperii

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