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(2-Amino-3-nitrobenzoato-κO)triphenyltin(IV)
The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent molecules. In each molecule, the four-coordinated Sn(IV) atom exists in a distorted tetrahedral geometry and two intramolecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In o...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089114/ https://www.ncbi.nlm.nih.gov/pubmed/21754293 http://dx.doi.org/10.1107/S160053681101244X |
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author | Win, Yip-Foo Choong, Chen-Shang Heng, Mei-Hsuan Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Win, Yip-Foo Choong, Chen-Shang Heng, Mei-Hsuan Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Win, Yip-Foo |
collection | PubMed |
description | The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent molecules. In each molecule, the four-coordinated Sn(IV) atom exists in a distorted tetrahedral geometry and two intramolecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In one molecule, the benzene ring of the 2-amino-3-nitrobenzoate ligand makes dihedral angles of 42.74 (11), 89.66 (13) and 53.04 (10)° with the three phenyl rings. The corresponding dihedral angles for the other molecule are 6.29 (11), 66.55 (11) and 62.33 (10)°. In the crystal, a weak intermolecular C—H⋯π interaction and a π–π stacking interaction with a centroid–centroid distance of 3.5877 (12) Å are observed. |
format | Text |
id | pubmed-3089114 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891142011-07-13 (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) Win, Yip-Foo Choong, Chen-Shang Heng, Mei-Hsuan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent molecules. In each molecule, the four-coordinated Sn(IV) atom exists in a distorted tetrahedral geometry and two intramolecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In one molecule, the benzene ring of the 2-amino-3-nitrobenzoate ligand makes dihedral angles of 42.74 (11), 89.66 (13) and 53.04 (10)° with the three phenyl rings. The corresponding dihedral angles for the other molecule are 6.29 (11), 66.55 (11) and 62.33 (10)°. In the crystal, a weak intermolecular C—H⋯π interaction and a π–π stacking interaction with a centroid–centroid distance of 3.5877 (12) Å are observed. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089114/ /pubmed/21754293 http://dx.doi.org/10.1107/S160053681101244X Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Heng, Mei-Hsuan Quah, Ching Kheng Fun, Hoong-Kun (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title | (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title_full | (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title_fullStr | (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title_full_unstemmed | (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title_short | (2-Amino-3-nitrobenzoato-κO)triphenyltin(IV) |
title_sort | (2-amino-3-nitrobenzoato-κo)triphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089114/ https://www.ncbi.nlm.nih.gov/pubmed/21754293 http://dx.doi.org/10.1107/S160053681101244X |
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