Cargando…

(2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)

The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent mol­ecules. In each mol­ecule, the four-coordinated Sn(IV) atom exists in a distorted tetra­hedral geometry and two intra­molecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In o...

Descripción completa

Detalles Bibliográficos
Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Heng, Mei-Hsuan, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089114/
https://www.ncbi.nlm.nih.gov/pubmed/21754293
http://dx.doi.org/10.1107/S160053681101244X
_version_ 1782202980917837824
author Win, Yip-Foo
Choong, Chen-Shang
Heng, Mei-Hsuan
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Heng, Mei-Hsuan
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent mol­ecules. In each mol­ecule, the four-coordinated Sn(IV) atom exists in a distorted tetra­hedral geometry and two intra­molecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In one mol­ecule, the benzene ring of the 2-amino-3-nitro­benzoate ligand makes dihedral angles of 42.74 (11), 89.66 (13) and 53.04 (10)° with the three phenyl rings. The corresponding dihedral angles for the other mol­ecule are 6.29 (11), 66.55 (11) and 62.33 (10)°. In the crystal, a weak inter­molecular C—H⋯π inter­action and a π–π stacking inter­action with a centroid–centroid distance of 3.5877 (12) Å are observed.
format Text
id pubmed-3089114
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30891142011-07-13 (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV) Win, Yip-Foo Choong, Chen-Shang Heng, Mei-Hsuan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))], consists of two independent mol­ecules. In each mol­ecule, the four-coordinated Sn(IV) atom exists in a distorted tetra­hedral geometry and two intra­molecular N—H⋯O hydrogen bonds with S(6) ring motifs are present. In one mol­ecule, the benzene ring of the 2-amino-3-nitro­benzoate ligand makes dihedral angles of 42.74 (11), 89.66 (13) and 53.04 (10)° with the three phenyl rings. The corresponding dihedral angles for the other mol­ecule are 6.29 (11), 66.55 (11) and 62.33 (10)°. In the crystal, a weak inter­molecular C—H⋯π inter­action and a π–π stacking inter­action with a centroid–centroid distance of 3.5877 (12) Å are observed. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089114/ /pubmed/21754293 http://dx.doi.org/10.1107/S160053681101244X Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Heng, Mei-Hsuan
Quah, Ching Kheng
Fun, Hoong-Kun
(2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_full (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_fullStr (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_full_unstemmed (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_short (2-Amino-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_sort (2-amino-3-nitro­benzoato-κo)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089114/
https://www.ncbi.nlm.nih.gov/pubmed/21754293
http://dx.doi.org/10.1107/S160053681101244X
work_keys_str_mv AT winyipfoo 2amino3nitrobenzoatokotriphenyltiniv
AT choongchenshang 2amino3nitrobenzoatokotriphenyltiniv
AT hengmeihsuan 2amino3nitrobenzoatokotriphenyltiniv
AT quahchingkheng 2amino3nitrobenzoatokotriphenyltiniv
AT funhoongkun 2amino3nitrobenzoatokotriphenyltiniv