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Tris(ethylenediamine)cobalt(III) diformatodioxalatoindate(III) dihydrate
In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co—N bond lengths lie in the range 1.960 (5)–1.997 (5) Å. In the anion, the In(III) atom is coordinated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089116/ https://www.ncbi.nlm.nih.gov/pubmed/21754305 http://dx.doi.org/10.1107/S1600536811013109 |
| Sumario: | In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co—N bond lengths lie in the range 1.960 (5)–1.997 (5) Å. In the anion, the In(III) atom is coordinated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octahedral geometry. Intermolecular O—H⋯O and N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water molecules into three-dimensional structure. |
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