Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate

In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co—N bond lengths lie in the range 1.960 (5)–1.997 (5) Å. In the anion, the In(III) atom is coordin­ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted...

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Detalles Bibliográficos
Autores principales: Tong, Juying, Pan, Qinhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089116/
https://www.ncbi.nlm.nih.gov/pubmed/21754305
http://dx.doi.org/10.1107/S1600536811013109
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author Tong, Juying
Pan, Qinhe
author_facet Tong, Juying
Pan, Qinhe
author_sort Tong, Juying
collection PubMed
description In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co—N bond lengths lie in the range 1.960 (5)–1.997 (5) Å. In the anion, the In(III) atom is coordin­ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa­hedral geometry. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water mol­ecules into three-dimensional structure.
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spelling pubmed-30891162011-07-13 Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate Tong, Juying Pan, Qinhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co—N bond lengths lie in the range 1.960 (5)–1.997 (5) Å. In the anion, the In(III) atom is coordin­ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa­hedral geometry. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water mol­ecules into three-dimensional structure. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089116/ /pubmed/21754305 http://dx.doi.org/10.1107/S1600536811013109 Text en © Tong and Pan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tong, Juying
Pan, Qinhe
Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title_full Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title_fullStr Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title_full_unstemmed Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title_short Tris(ethyl­enediamine)­cobalt(III) diformatodioxalatoindate(III) dihydrate
title_sort tris(ethyl­enediamine)­cobalt(iii) diformatodioxalatoindate(iii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089116/
https://www.ncbi.nlm.nih.gov/pubmed/21754305
http://dx.doi.org/10.1107/S1600536811013109
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AT panqinhe trisethylenediaminecobaltiiidiformatodioxalatoindateiiidihydrate

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