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4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one
The whole molecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respective...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089123/ https://www.ncbi.nlm.nih.gov/pubmed/21754365 http://dx.doi.org/10.1107/S1600536811011676 |
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author | Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_facet | Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_sort | Asad, Mohammad |
collection | PubMed |
description | The whole molecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respectively. In both components, a pair of intramolecular O—H⋯O interactions generate rings of S(8) graph-set motif. In the crystal, the molecules are linked by intermolecular C—H⋯O interactions, forming chains along the b axis. The structure is further stabilized by π–π interactions with centroid–centroid distances of 3.594 (2) and 3.608 (5) Å. |
format | Text |
id | pubmed-3089123 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891232011-07-13 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The whole molecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respectively. In both components, a pair of intramolecular O—H⋯O interactions generate rings of S(8) graph-set motif. In the crystal, the molecules are linked by intermolecular C—H⋯O interactions, forming chains along the b axis. The structure is further stabilized by π–π interactions with centroid–centroid distances of 3.594 (2) and 3.608 (5) Å. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089123/ /pubmed/21754365 http://dx.doi.org/10.1107/S1600536811011676 Text en © Asad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title | 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title_full | 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title_fullStr | 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title_full_unstemmed | 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title_short | 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-3-chromenyl)(3-thienyl)methyl]-2H-chromen-2-one |
title_sort | 4-hydroxy-3-[(4-hydroxy-2-oxo-2h-3-chromenyl)(3-thienyl)methyl]-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089123/ https://www.ncbi.nlm.nih.gov/pubmed/21754365 http://dx.doi.org/10.1107/S1600536811011676 |
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