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4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one

The whole mol­ecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respective...

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Detalles Bibliográficos
Autores principales: Asad, Mohammad, Oo, Chuan-Wei, Osman, Hasnah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089123/
https://www.ncbi.nlm.nih.gov/pubmed/21754365
http://dx.doi.org/10.1107/S1600536811011676
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author Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Asad, Mohammad
collection PubMed
description The whole mol­ecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respectively. In both components, a pair of intra­molecular O—H⋯O inter­actions generate rings of S(8) graph-set motif. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming chains along the b axis. The structure is further stabilized by π–π inter­actions with centroid–centroid distances of 3.594 (2) and 3.608 (5) Å.
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spelling pubmed-30891232011-07-13 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The whole mol­ecule of the title compound, C(23)H(14)O(6)S, is disordered over two sets of sites with refined occupancies of 0.8733 (12):0.1267 (12). The dihedral angle between the mean planes through the chromene ring systems is 56.31 (5) and 55.2 (3)° for the major and minor components, respectively. In both components, a pair of intra­molecular O—H⋯O inter­actions generate rings of S(8) graph-set motif. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming chains along the b axis. The structure is further stabilized by π–π inter­actions with centroid–centroid distances of 3.594 (2) and 3.608 (5) Å. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089123/ /pubmed/21754365 http://dx.doi.org/10.1107/S1600536811011676 Text en © Asad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title_full 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title_fullStr 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title_full_unstemmed 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title_short 4-Hy­droxy-3-[(4-hy­droxy-2-oxo-2H-3-chromen­yl)(3-thien­yl)meth­yl]-2H-chromen-2-one
title_sort 4-hy­droxy-3-[(4-hy­droxy-2-oxo-2h-3-chromen­yl)(3-thien­yl)meth­yl]-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089123/
https://www.ncbi.nlm.nih.gov/pubmed/21754365
http://dx.doi.org/10.1107/S1600536811011676
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