4-Nitro-N-(4-nitro­benzo­yl)benzamide

The central acetyl­acetamide moiety in the title compound, C(14)H(9)N(3)O(6), is buckled [e.g. the C—N—C—O torsion angle is 14.3 (6)°] but the r.m.s. deviation for the five atoms is 0.044 Å. The benzene rings lie on the same side of the central plane, forming dihedral angles of 37.17 (15) and 28.58 ...

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Detalles Bibliográficos
Autores principales: Saeed, Sohail, Rashid, Naghmana, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089125/
https://www.ncbi.nlm.nih.gov/pubmed/21754496
http://dx.doi.org/10.1107/S1600536811014450
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author Saeed, Sohail
Rashid, Naghmana
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Saeed, Sohail
Rashid, Naghmana
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Saeed, Sohail
collection PubMed
description The central acetyl­acetamide moiety in the title compound, C(14)H(9)N(3)O(6), is buckled [e.g. the C—N—C—O torsion angle is 14.3 (6)°] but the r.m.s. deviation for the five atoms is 0.044 Å. The benzene rings lie on the same side of the central plane, forming dihedral angles of 37.17 (15) and 28.58 (19)° with it. The dihedral angle between the two rings is 17.8 (2)° indicating that the mol­ecule is curved. The carbonyl groups are syn to each other and anti to the amino H atom. This allows for the formation of N—H⋯O hydrogen bonds in the crystal, which leads to twisted chains along the b axis. Positional disorder (50:50) of the O atoms was modelled for both the nitro groups.
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spelling pubmed-30891252011-07-13 4-Nitro-N-(4-nitro­benzo­yl)benzamide Saeed, Sohail Rashid, Naghmana Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The central acetyl­acetamide moiety in the title compound, C(14)H(9)N(3)O(6), is buckled [e.g. the C—N—C—O torsion angle is 14.3 (6)°] but the r.m.s. deviation for the five atoms is 0.044 Å. The benzene rings lie on the same side of the central plane, forming dihedral angles of 37.17 (15) and 28.58 (19)° with it. The dihedral angle between the two rings is 17.8 (2)° indicating that the mol­ecule is curved. The carbonyl groups are syn to each other and anti to the amino H atom. This allows for the formation of N—H⋯O hydrogen bonds in the crystal, which leads to twisted chains along the b axis. Positional disorder (50:50) of the O atoms was modelled for both the nitro groups. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089125/ /pubmed/21754496 http://dx.doi.org/10.1107/S1600536811014450 Text en © Saeed et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Sohail
Rashid, Naghmana
Ng, Seik Weng
Tiekink, Edward R. T.
4-Nitro-N-(4-nitro­benzo­yl)benzamide
title 4-Nitro-N-(4-nitro­benzo­yl)benzamide
title_full 4-Nitro-N-(4-nitro­benzo­yl)benzamide
title_fullStr 4-Nitro-N-(4-nitro­benzo­yl)benzamide
title_full_unstemmed 4-Nitro-N-(4-nitro­benzo­yl)benzamide
title_short 4-Nitro-N-(4-nitro­benzo­yl)benzamide
title_sort 4-nitro-n-(4-nitro­benzo­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089125/
https://www.ncbi.nlm.nih.gov/pubmed/21754496
http://dx.doi.org/10.1107/S1600536811014450
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AT rashidnaghmana 4nitron4nitrobenzoylbenzamide
AT ngseikweng 4nitron4nitrobenzoylbenzamide
AT tiekinkedwardrt 4nitron4nitrobenzoylbenzamide

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