Butane-1,4-diammonium bis(perchlorate)

The butane-1,4-diammonium cation of the title compound, C(4)H(14)N(2) (2+)·2ClO(4) (−), lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structur...

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Detalles Bibliográficos
Autores principales: Arderne, Charmaine, Kruger, Gert J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089126/
https://www.ncbi.nlm.nih.gov/pubmed/21754386
http://dx.doi.org/10.1107/S1600536811012025
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author Arderne, Charmaine
Kruger, Gert J.
author_facet Arderne, Charmaine
Kruger, Gert J.
author_sort Arderne, Charmaine
collection PubMed
description The butane-1,4-diammonium cation of the title compound, C(4)H(14)N(2) (2+)·2ClO(4) (−), lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated inter­actions to the perchlorate anion. Complex hydrogen-bonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R (10) (10)(50) is identified.
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spelling pubmed-30891262011-07-13 Butane-1,4-diammonium bis(perchlorate) Arderne, Charmaine Kruger, Gert J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The butane-1,4-diammonium cation of the title compound, C(4)H(14)N(2) (2+)·2ClO(4) (−), lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated inter­actions to the perchlorate anion. Complex hydrogen-bonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R (10) (10)(50) is identified. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089126/ /pubmed/21754386 http://dx.doi.org/10.1107/S1600536811012025 Text en © Arderne and Kruger 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arderne, Charmaine
Kruger, Gert J.
Butane-1,4-diammonium bis(perchlorate)
title Butane-1,4-diammonium bis(perchlorate)
title_full Butane-1,4-diammonium bis(perchlorate)
title_fullStr Butane-1,4-diammonium bis(perchlorate)
title_full_unstemmed Butane-1,4-diammonium bis(perchlorate)
title_short Butane-1,4-diammonium bis(perchlorate)
title_sort butane-1,4-diammonium bis(perchlorate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089126/
https://www.ncbi.nlm.nih.gov/pubmed/21754386
http://dx.doi.org/10.1107/S1600536811012025
work_keys_str_mv AT ardernecharmaine butane14diammoniumbisperchlorate
AT krugergertj butane14diammoniumbisperchlorate

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