[(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)

In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl­aldehyde benzoyl­hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu—O a...

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Detalles Bibliográficos
Autores principales: Wang, Yu-Min, Lin, Xiao-Hui, Chen, Zhen, Jiang, Hong-Li, Zhang, Chang-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089131/
https://www.ncbi.nlm.nih.gov/pubmed/21754268
http://dx.doi.org/10.1107/S1600536811009901
Descripción
Sumario:In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl­aldehyde benzoyl­hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu—O and Cu—N bond lengths of 1.926 and 1.976 Å, respectively. The pyridine ring makes dihedral angles of 26.12 (13) and 11.08 (12)°, respectively, with the trimeth­oxy­phenyl and phenolate rings, which make a dihedral angle of 16.05 (12)° with one another.

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