[(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)

In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl­aldehyde benzoyl­hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu—O a...

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Detalles Bibliográficos
Autores principales: Wang, Yu-Min, Lin, Xiao-Hui, Chen, Zhen, Jiang, Hong-Li, Zhang, Chang-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089131/
https://www.ncbi.nlm.nih.gov/pubmed/21754268
http://dx.doi.org/10.1107/S1600536811009901
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author Wang, Yu-Min
Lin, Xiao-Hui
Chen, Zhen
Jiang, Hong-Li
Zhang, Chang-Jun
author_facet Wang, Yu-Min
Lin, Xiao-Hui
Chen, Zhen
Jiang, Hong-Li
Zhang, Chang-Jun
author_sort Wang, Yu-Min
collection PubMed
description In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl­aldehyde benzoyl­hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu—O and Cu—N bond lengths of 1.926 and 1.976 Å, respectively. The pyridine ring makes dihedral angles of 26.12 (13) and 11.08 (12)°, respectively, with the trimeth­oxy­phenyl and phenolate rings, which make a dihedral angle of 16.05 (12)° with one another.
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spelling pubmed-30891312011-07-13 [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II) Wang, Yu-Min Lin, Xiao-Hui Chen, Zhen Jiang, Hong-Li Zhang, Chang-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(17)H(15)ClN(2)O(5))(C(5)H(5)N)], the Cu(II) atom is coordinated by one N atom and two O atoms from an anionic salicyl­aldehyde benzoyl­hydrazone ligand and one pyridine N atom in a distorted square-planar geometry. The bonds displays the usual elongation with mean Cu—O and Cu—N bond lengths of 1.926 and 1.976 Å, respectively. The pyridine ring makes dihedral angles of 26.12 (13) and 11.08 (12)°, respectively, with the trimeth­oxy­phenyl and phenolate rings, which make a dihedral angle of 16.05 (12)° with one another. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089131/ /pubmed/21754268 http://dx.doi.org/10.1107/S1600536811009901 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yu-Min
Lin, Xiao-Hui
Chen, Zhen
Jiang, Hong-Li
Zhang, Chang-Jun
[(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title_full [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title_fullStr [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title_full_unstemmed [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title_short [(E)-N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) N′,O](pyridine-κN)copper(II)
title_sort [(e)-n′-(5-chloro-2-oxidobenzyl­idene-κo)-3,4,5-trimeth­oxy­benzohydrazidato-κ(2) n′,o](pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089131/
https://www.ncbi.nlm.nih.gov/pubmed/21754268
http://dx.doi.org/10.1107/S1600536811009901
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