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[μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)

The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two mol­ecules of the triangulo-triruthenium complex. The bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Alam, Mohd. Gulfam, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089132/
https://www.ncbi.nlm.nih.gov/pubmed/21754283
http://dx.doi.org/10.1107/S1600536811012050
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author Shawkataly, Omar bin
Alam, Mohd. Gulfam
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Alam, Mohd. Gulfam
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two mol­ecules of the triangulo-triruthenium complex. The bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphite ligand binds to the third Ru atom. Both the arsine and phosphite ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the pairs of benzene rings bound to individual As atoms are 85.67 (8) and 75.91 (8) in the first independent mol­ecule and 74.64 (8) and 70.76 (9) in the second. In the crystal, mol­ecules are linked into a three-dimensional framework by inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30891322011-07-13 [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0) Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two mol­ecules of the triangulo-triruthenium complex. The bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphite ligand binds to the third Ru atom. Both the arsine and phosphite ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the pairs of benzene rings bound to individual As atoms are 85.67 (8) and 75.91 (8) in the first independent mol­ecule and 74.64 (8) and 70.76 (9) in the second. In the crystal, mol­ecules are linked into a three-dimensional framework by inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089132/ /pubmed/21754283 http://dx.doi.org/10.1107/S1600536811012050 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Alam, Mohd. Gulfam
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title_full [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title_fullStr [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title_full_unstemmed [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title_short [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisoprop­yl phos­phite-3κP)-triangulo-triruthenium(0)
title_sort [μ-bis(diphenyl­arsanyl)methane-1:2κ(2) as:as′]nona­carbonyl-1κ(3)c,2κ(3)c,3κ(3)c-(triisoprop­yl phos­phite-3κp)-triangulo-triruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089132/
https://www.ncbi.nlm.nih.gov/pubmed/21754283
http://dx.doi.org/10.1107/S1600536811012050
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