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[μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0)
The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two molecules of the triangulo-triruthenium complex. The bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089132/ https://www.ncbi.nlm.nih.gov/pubmed/21754283 http://dx.doi.org/10.1107/S1600536811012050 |
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author | Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two molecules of the triangulo-triruthenium complex. The bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphite ligand binds to the third Ru atom. Both the arsine and phosphite ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the pairs of benzene rings bound to individual As atoms are 85.67 (8) and 75.91 (8) in the first independent molecule and 74.64 (8) and 70.76 (9) in the second. In the crystal, molecules are linked into a three-dimensional framework by intermolecular C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3089132 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891322011-07-13 [μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, Ru(3)(CO)(9)(μ-Ph(2)AsCH(2)AsPh(2))(P[OCH(CH(3))(2)](3)) or [Ru(3)(C(25)H(22)As(2))(C(9)H(21)O(3)P)(CO)(9)], contains two molecules of the triangulo-triruthenium complex. The bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphite ligand binds to the third Ru atom. Both the arsine and phosphite ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the pairs of benzene rings bound to individual As atoms are 85.67 (8) and 75.91 (8) in the first independent molecule and 74.64 (8) and 70.76 (9) in the second. In the crystal, molecules are linked into a three-dimensional framework by intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089132/ /pubmed/21754283 http://dx.doi.org/10.1107/S1600536811012050 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title_full | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title_fullStr | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title_full_unstemmed | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title_short | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triisopropyl phosphite-3κP)-triangulo-triruthenium(0) |
title_sort | [μ-bis(diphenylarsanyl)methane-1:2κ(2)
as:as′]nonacarbonyl-1κ(3)c,2κ(3)c,3κ(3)c-(triisopropyl phosphite-3κp)-triangulo-triruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089132/ https://www.ncbi.nlm.nih.gov/pubmed/21754283 http://dx.doi.org/10.1107/S1600536811012050 |
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