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(2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid

The 13 non-H atoms comprising the title compound, C(9)H(10)N(2)O(2), are close to planar (r.m.s. deviation = 0.140 Å), with maximum deviations of 0.292 (1) and 0.210 (1) Å to either side of the least-squares plane exhibited by the hy­droxy and carbonyl O atoms, respectively. The observed conformatio...

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Autores principales: Affan, Md. Abu, Salam, M. A., Siew, Eleazar Veronica, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089133/
https://www.ncbi.nlm.nih.gov/pubmed/21754470
http://dx.doi.org/10.1107/S1600536811013717
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author Affan, Md. Abu
Salam, M. A.
Siew, Eleazar Veronica
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Salam, M. A.
Siew, Eleazar Veronica
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description The 13 non-H atoms comprising the title compound, C(9)H(10)N(2)O(2), are close to planar (r.m.s. deviation = 0.140 Å), with maximum deviations of 0.292 (1) and 0.210 (1) Å to either side of the least-squares plane exhibited by the hy­droxy and carbonyl O atoms, respectively. The observed conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond. The conformation about the N=C double bond [1.2909 (16) Å] is E. The hy­droxy OH group also forms an inter­molecular hydrogen bond to a carbonyl O atom, and the amine H atom similarly forms an N—H⋯O hydrogen bond to a second carbonyl O atom. The result is the formation of a double layer with a flat topology. Layers stack along the a-axis direction connected by C—H⋯π inter­actions.
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spelling pubmed-30891332011-07-13 (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid Affan, Md. Abu Salam, M. A. Siew, Eleazar Veronica Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 13 non-H atoms comprising the title compound, C(9)H(10)N(2)O(2), are close to planar (r.m.s. deviation = 0.140 Å), with maximum deviations of 0.292 (1) and 0.210 (1) Å to either side of the least-squares plane exhibited by the hy­droxy and carbonyl O atoms, respectively. The observed conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond. The conformation about the N=C double bond [1.2909 (16) Å] is E. The hy­droxy OH group also forms an inter­molecular hydrogen bond to a carbonyl O atom, and the amine H atom similarly forms an N—H⋯O hydrogen bond to a second carbonyl O atom. The result is the formation of a double layer with a flat topology. Layers stack along the a-axis direction connected by C—H⋯π inter­actions. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089133/ /pubmed/21754470 http://dx.doi.org/10.1107/S1600536811013717 Text en © Affan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Affan, Md. Abu
Salam, M. A.
Siew, Eleazar Veronica
Ng, Seik Weng
Tiekink, Edward R. T.
(2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title_full (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title_fullStr (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title_full_unstemmed (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title_short (2E)-2-(2-Phenyl­hydrazin-1-yl­idene)propanoic acid
title_sort (2e)-2-(2-phenyl­hydrazin-1-yl­idene)propanoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089133/
https://www.ncbi.nlm.nih.gov/pubmed/21754470
http://dx.doi.org/10.1107/S1600536811013717
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