Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate

In the title complex, [Co(CN)(2)(C(18)H(18)N(4))]PF(6), the Co(III) atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The Co(III) atom exhibits an octa­hedral geometry, coordinated by four N atoms fro...

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Detalles Bibliográficos
Autores principales: Yu, Fan, Li, Bao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089135/
https://www.ncbi.nlm.nih.gov/pubmed/21754296
http://dx.doi.org/10.1107/S1600536811012001
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author Yu, Fan
Li, Bao
author_facet Yu, Fan
Li, Bao
author_sort Yu, Fan
collection PubMed
description In the title complex, [Co(CN)(2)(C(18)H(18)N(4))]PF(6), the Co(III) atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The Co(III) atom exhibits an octa­hedral geometry, coordinated by four N atoms from the tris­(2-pyridyl­meth­yl)amine ligand with an average Co—N distance of 1.953 (2) Å, and two cyanide C atoms with an average Co—C distance of 1.895 (2) Å. The crystal packing is stabilized by inter­molecular C—H⋯N and C—H⋯F inter­actions.
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spelling pubmed-30891352011-07-13 Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate Yu, Fan Li, Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(CN)(2)(C(18)H(18)N(4))]PF(6), the Co(III) atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The Co(III) atom exhibits an octa­hedral geometry, coordinated by four N atoms from the tris­(2-pyridyl­meth­yl)amine ligand with an average Co—N distance of 1.953 (2) Å, and two cyanide C atoms with an average Co—C distance of 1.895 (2) Å. The crystal packing is stabilized by inter­molecular C—H⋯N and C—H⋯F inter­actions. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089135/ /pubmed/21754296 http://dx.doi.org/10.1107/S1600536811012001 Text en © Yu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Fan
Li, Bao
Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title_full Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title_fullStr Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title_full_unstemmed Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title_short Dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(III) hexa­fluorido­phosphate
title_sort dicyanido[tris­(2-pyridyl­meth­yl)amine]­cobalt(iii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089135/
https://www.ncbi.nlm.nih.gov/pubmed/21754296
http://dx.doi.org/10.1107/S1600536811012001
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AT libao dicyanidotris2pyridylmethylaminecobaltiiihexafluoridophosphate

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