Bis{2-[4-(methyl­sulfan­yl)phen­yl]-1H-benzimidazol-3-ium} tetra­bromido­cuprate(II) dihydrate

The asymmetric unit of the title compound, (C(14)H(13)N(2)S)(2)[CuBr(4)]·2H(2)O, contains two cations, one anion and two solvent water mol­ecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fash...

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Detalles Bibliográficos
Autores principales: Manjunatha, M. N., Ziaulla, Mohamed, Sankolli, Ravish, Begum, Noor Shahina, Nagasundara, K. R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089137/
https://www.ncbi.nlm.nih.gov/pubmed/21754304
http://dx.doi.org/10.1107/S1600536811012840
Descripción
Sumario:The asymmetric unit of the title compound, (C(14)H(13)N(2)S)(2)[CuBr(4)]·2H(2)O, contains two cations, one anion and two solvent water mol­ecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fashion and form stacks along [100]. The central Cu(II) atom of the anion is in a distorted tetra­hedral environment.

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