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Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate
The asymmetric unit of the title compound, (C(14)H(13)N(2)S)(2)[CuBr(4)]·2H(2)O, contains two cations, one anion and two solvent water molecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fash...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089137/ https://www.ncbi.nlm.nih.gov/pubmed/21754304 http://dx.doi.org/10.1107/S1600536811012840 |
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author | Manjunatha, M. N. Ziaulla, Mohamed Sankolli, Ravish Begum, Noor Shahina Nagasundara, K. R. |
author_facet | Manjunatha, M. N. Ziaulla, Mohamed Sankolli, Ravish Begum, Noor Shahina Nagasundara, K. R. |
author_sort | Manjunatha, M. N. |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(14)H(13)N(2)S)(2)[CuBr(4)]·2H(2)O, contains two cations, one anion and two solvent water molecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fashion and form stacks along [100]. The central Cu(II) atom of the anion is in a distorted tetrahedral environment. |
format | Text |
id | pubmed-3089137 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30891372011-07-13 Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate Manjunatha, M. N. Ziaulla, Mohamed Sankolli, Ravish Begum, Noor Shahina Nagasundara, K. R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(14)H(13)N(2)S)(2)[CuBr(4)]·2H(2)O, contains two cations, one anion and two solvent water molecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fashion and form stacks along [100]. The central Cu(II) atom of the anion is in a distorted tetrahedral environment. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089137/ /pubmed/21754304 http://dx.doi.org/10.1107/S1600536811012840 Text en © Manjunatha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Manjunatha, M. N. Ziaulla, Mohamed Sankolli, Ravish Begum, Noor Shahina Nagasundara, K. R. Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title_full | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title_fullStr | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title_full_unstemmed | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title_short | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocuprate(II) dihydrate |
title_sort | bis{2-[4-(methylsulfanyl)phenyl]-1h-benzimidazol-3-ium} tetrabromidocuprate(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089137/ https://www.ncbi.nlm.nih.gov/pubmed/21754304 http://dx.doi.org/10.1107/S1600536811012840 |
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